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Titlebook: Ga Organogallium Compounds; Part 1 Jean-Claude Maire,Ulrich Krüerke,Christa Siebert,U Book 1986Latest edition Springer-Verlag Berlin Heidel

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21#
發(fā)表于 2025-3-25 05:35:54 | 只看該作者
https://doi.org/10.1007/978-3-030-99295-8l and solvent (pumping at -15°C for 2 d), followed by distillation at 25 to 30°C under high vacuum, yielded a colorless liquid consisting of a mixture of the compound (76%) and Ga(CH.).H (based on analyses). The products could not be separated because Ga(CH.).GeH. decomposes slowly at 25°C to give Ga(CH.).H and (GeH.)..
22#
發(fā)表于 2025-3-25 11:03:21 | 只看該作者
23#
發(fā)表于 2025-3-25 13:36:58 | 只看該作者
24#
發(fā)表于 2025-3-25 17:10:07 | 只看該作者
25#
發(fā)表于 2025-3-25 20:55:00 | 只看該作者
26#
發(fā)表于 2025-3-26 02:27:25 | 只看該作者
A Revision of the Genus Acromastiguma(CH.). by heating in a higher boiling ether [22]. The preparation of solvent-free Ga(CH.). from GaCl. and CH.MgI in O(C.H.-i). in a 68% yield has been claimed in [44]. The Grignard solution containing an excess of CH.I can also be electrolyzed using a Ga-pool anode and a Pt cathode to give Ga(CH.).
27#
發(fā)表于 2025-3-26 06:14:38 | 只看該作者
A Revolution in Economic Theory5 Torr total pressure [3]). The composition of the colorless, highly viscous product was concluded from the supposedly quantitative thermal decomposition at 180°C to Ga(CH.)., H., and Ga metal [1, 2]. However, later workers were unable to isolate a uniform compound from the discharge. Their viscous
28#
發(fā)表于 2025-3-26 08:46:37 | 只看該作者
https://doi.org/10.1007/978-3-319-09931-6ysis is proceeding slowly. The rate of reaction can be regulated by controlling the temperature [2]. A checked version of this procedure with an 80% yield, starting with the in situ preparation of the etherate from GaCl. and LiCH. in ether at -78°C, is published in [8]. The resulting reaction mixtur
29#
發(fā)表于 2025-3-26 14:43:44 | 只看該作者
In Case of Emergency: Capital Requirements,rivatives contain potentially chelating ligands (Nos. 7 to 12 and No. 22), including chelating S N systems where it is impossible to distinguish between covalent and coordinative bonds to either the S or N atom. Derivatives of monothiocarboxylic acids, GaR.OC(S)R’. have already been described with t
30#
發(fā)表于 2025-3-26 20:29:49 | 只看該作者
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