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Titlebook: Ga Organogallium Compounds; Part 1 Jean-Claude Maire,Ulrich Krüerke,Christa Siebert,U Book 1986Latest edition Springer-Verlag Berlin Heidel

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書目名稱Ga Organogallium Compounds
副標(biāo)題Part 1
編輯Jean-Claude Maire,Ulrich Krüerke,Christa Siebert,U
視頻videohttp://file.papertrans.cn/381/380196/380196.mp4
叢書名稱Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition
圖書封面Titlebook: Ga Organogallium Compounds; Part 1 Jean-Claude Maire,Ulrich Krüerke,Christa Siebert,U Book 1986Latest edition Springer-Verlag Berlin Heidel
描述The present volume describes all organogallium compounds, i.e., compounds containing at least one gallium-carbon bond. It covers the literature completely.to the end of 1984 and includes many references to the literature up to the end of 1985. The organic chemistry of gallium is largely dominated by compounds of the types GaR3 (Chapter 1), GaR X _ (Chapters 2 to 12), and M[GaRnX4_nl (M = cation, Chapter 13), where X n 3 n stands for a non-carbon atom or any organic or organometallic group bonded to gallium through a non-carbon atom. The arrangement of GaR X - and M[GaRnX"_nlcompounds by n 3 n the kind of Ga-X bond is evident from the table of contents on pp. XI to XIV. The extensive use of pyrazolyl-containing organogallium anions as polydentate donor ligands in transition metal compounds resulted in a particularly voluminous chapter on anions with Ga-N bonds (13.6). The volume is concluded by a few low-valence organogallium compounds (Chapter 14) that (I) atom and an aromatic ligand in an TJe fashion. exhibit bonding interaction between a gallium Due to a free coordination site at the Ga atom, neutral compounds form many adducts with Lewis bases (symbol D). These adducts are descr
出版日期Book 1986Latest edition
關(guān)鍵詞Bindungen; chemical bond; chemistry; metals; organic chemistry; transition metal
版次8
doihttps://doi.org/10.1007/978-3-662-07374-2
isbn_ebook978-3-662-07374-2
copyrightSpringer-Verlag Berlin Heidelberg 1986
The information of publication is updating

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Organogallium Hydrides,5 Torr total pressure [3]). The composition of the colorless, highly viscous product was concluded from the supposedly quantitative thermal decomposition at 180°C to Ga(CH.)., H., and Ga metal [1, 2]. However, later workers were unable to isolate a uniform compound from the discharge. Their viscous
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Organogallium-Sulfur Compounds,rivatives contain potentially chelating ligands (Nos. 7 to 12 and No. 22), including chelating S N systems where it is impossible to distinguish between covalent and coordinative bonds to either the S or N atom. Derivatives of monothiocarboxylic acids, GaR.OC(S)R’. have already been described with t
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Organogallium-Boron Compounds,, Ga(CH.). was allowed to react with a fivefold excess of B.H. at -15°C for 3 h and was isolated in a 20 to 42% yield by trap-to-trap distillation of the volatiles in a vacuum system [6]. An 80% yield was obtained from the reaction of Ga(CH.).Cl with an excess of powdered LiBH. at -15°C with pumping
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Compounds of Organogallium Anions,[GaR.]., and is followed by [GaR.X.]. anions (n = 1 to 3) where X stands for hydrogen, halogen, pseudohalogen, oxygen groups, etc. Finally, very extended subsections deal with organogallium pyrazolyl anions bonded to transition metal fragments via the second N atom of pyrazolyl, thus acting as anion
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