Titlebook: Elementary Reaction Steps in Heterogeneous Catalysis; R. W. Joyner,R. A. Santen Book 1993 Springer Science+Business Media Dordrecht 1993 I

長(zhǎng)矛

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Surface Science as a Basis for Understanding Heterogeneous Catalysisf the cluster-like bonding of molecular adsorbates of thermal activation and the unique reactivity of oxide-metal interfaces. Correlations of catalytic reaction and surface science studies are providing new concepts and models of heterogeneous catalysis.

Madrigal

artifice

Session Three, ,ssion tomography and the wider use of radio-active isotopes in studies on the mechanism, were therefore outside the scope of the workshop. However, the choice of the techniques to be discussed was not just incidental and the discussion confirmed the merits and a good future for the above mentioned techniques in catalysis.

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https://doi.org/10.1057/9781137287427mparison to strictly molecular systems, heterogeneous catalysts are intrinsically much more complicated. In addition, the application of physical methods to structural and mechanistic problems of heterogeneous systems, as well as interpretation of the results, can be difficult.

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https://doi.org/10.1007/978-1-349-19286-1c bond-fission reactions; real turnover numbers are much higher than usually estimated. All of this is part of a general thesis where the catalytic behaviour of metals not only relates directly to that of metalla-enzymes and synthetic organometallic complexes but also shows many fundamental similarities to catalysis by refractory oxides.