Titlebook: Elementary Reaction Steps in Heterogeneous Catalysis; R. W. Joyner,R. A. Santen Book 1993 Springer Science+Business Media Dordrecht 1993 I

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Surface Science as a Basis for Understanding Heterogeneous Catalysisehavior. These include trends of reactivity and bonding across the periodic table; the observation that rough surfaces and defect sites have high reaction rates and more strongly bind the adsorbates; the reaction and chemisorption induced restructuring of metal surfaces; and the presence of a strong

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Organometallic Chemistry as a Basis for Understanding Heterogeneous Catalysisl product distribution is known, while the nature of the catalyst-reactant interactions remains obscure. In a few cases, more detailed mechanistic proposals have been advanced, but they remain modest in scope compared to the detailed mechanisms that have been developed in molecular organic chemistry

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The Organic Chemical Approach to Heterogeneous Catalysisast half century. A convincing case is provided that the site densities are low and very often mononuclear rather than ensembles of two or more contiguous atoms. The mechanisms of reaction are then due to the interconversion of various transient intermediates as ligands of these mononuclear centres,

天真

Electrochemical Activation of Catalysed ReactionsY.O.-doped-ZrO., an O. conductor, or β“-Al.O., a Na. conductor, and by supplying or removing ions to or from the metal catalyst surface via application of an external voltage. The induced change in catalytic rate can be up to 3 ×0. times higher than the rate of ion supply and up to 70 times higher t

Calculus

Selective Oxidation Pathways at Oxide Surfaces: The Transformation of Alkanes on Vanadyl Pyrophosphaed in relation to the results reported in the literature on the nature of active sites and mechanisms of reaction in alkene selective oxidation, in order to evidence which new aspects about the elementary steps, selective oxidation pathways and surface characteristics of oxide catalysts derive from

Calculus

Exonerate

biosphere

Adsorption and Reactions of CO, NO, H2 and O2 on Group VIII Metal Surfacesthe differences in behaviour of the Group VIII metal surfaces in reactions of oxygen with hydrogen and carbon monoxide; nitric oxide with hydrogen and carbon monoxide; carbon monoxide with hydrogen; and ammonia with nitric oxide and oxygen. It will be shown that the differences in activity and selec

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