Titlebook: Organolithiums in Enantioselective Synthesis; David M. Hodgson Book 2003 Springer-Verlag Berlin Heidelberg 2003 Metalorganic Chemistry.che

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Organolithiums in Enantioselective Synthesis978-3-540-36117-6Series ISSN 1436-6002 Series E-ISSN 1616-8534

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Enantioselective Synthesis by Lithiation Adjacent to Oxygen and Subsequent Rearrangement,s field is presented. The first section concerns asymmetric Wittig rearrangements. Asymmetric retro-Brook rearrangements are then covered, followed by rearrangements of phosphate to phosphonate. The last section reviews asymmetric rearrangements of lithiated epoxides.

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Enantioselective Synthesis by Lithiation to Generate Planar or Axial Chirality,laying these stereochemical features are ferrocenes, arenechromium tricarbonyl complexes, biaryls, atropisomeric amides and allenes. Methods for the enantioselective lithiation of these compound classes, relying on either substrate (chiral auxiliary) or reagent (chiral base) control will be reviewed.

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