Titlebook: Organolithiums in Enantioselective Synthesis; David M. Hodgson Book 2003 Springer-Verlag Berlin Heidelberg 2003 Metalorganic Chemistry.che

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ADOPT

Enantioselective Synthesis by Lithiation Adjacent to Nitrogen and Electrophile Incorporation, with a single chiral ligand and diastereoselective and enantioselective conjugate additions with benzylic and allylic lithiation intermediates. The sequences are classified, where information is available, in terms of stereocontrol in the lithiation or substitution step.

crescendo

Book 2003n inspiration for future developments. Following an overview chapter summarising the key milestones, successive chapters, each written by leading experts in their field, critically survey all the major areas of progress..

DUST

衣服

Enantioselective Conjugate Addition and 1,2-Addition to C=N of Organolithium Reagents,ine chemistry is also briefly presented. Sect. 2 summarizes the 1,2-additions to imines and imine congeners (hydrazones, oxime ethers, nitrones) using chiral auxiliaries and chiral ligands. We do not describe additions which use chiral auxiliary groups in carbonyl compounds.

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QUAIL

Enantioselective Addition of Organolithiums to C=O Groups and Ethers,es and ketones) or enantioselective cleavages of C-O units in strained ethers (i.e., epoxides and oxetanes) as well as in acetals. The achievement of high enantioselectivities is desirable and hence factors controlling these enantioselectivities are subjects of intensive research. Beneficial externa

Myosin

Enantioselective Conjugate Addition and 1,2-Addition to C=N of Organolithium Reagents, reactions of organolithium reagents constitutes a remarkable area of fundamental progresses in recent synthetic organic chemistry. The conjugate addition (or Michael reaction, 1,4-addition) and 1,2-addition to C= N double bonds are powerful methods for forming a carbon-carbon bond. This chapter rev