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Titlebook: Organolithiums in Enantioselective Synthesis; David M. Hodgson Book 2003 Springer-Verlag Berlin Heidelberg 2003 Metalorganic Chemistry.che

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書目名稱Organolithiums in Enantioselective Synthesis
編輯David M. Hodgson
視頻videohttp://file.papertrans.cn/705/704498/704498.mp4
概述Each volume of Topics in Organometallic Chemistry provides the broad scientific readership with comprehensive summary and critical overview of a topic in organometallic chemistry..Research in this rap
叢書名稱Topics in Organometallic Chemistry
圖書封面Titlebook: Organolithiums in Enantioselective Synthesis;  David M. Hodgson Book 2003 Springer-Verlag Berlin Heidelberg 2003 Metalorganic Chemistry.che
描述.Organolithium chemistry occupies a central position in the selective construction of C-C bonds in both simple and complex molecules. Paralleling the surge of interest in methods for asymmetric synthesis, the use of organolithiums in enantioselective synthesis has witnessed spectacular advances in a little over a decade. This volume is the first dedicated to a comprehensive coverage of this important area.?It is designed to?provide graduate students and researchers with a rich source of essential information on synthesising molecules in an enantioselective manner using organolithiums, and be an inspiration for future developments. Following an overview chapter summarising the key milestones, successive chapters, each written by leading experts in their field, critically survey all the major areas of progress..
出版日期Book 2003
關鍵詞Metalorganic Chemistry; chemistry; gold; inorganic chemistry; lithium; molecule; organic chemistry; oxygen;
版次1
doihttps://doi.org/10.1007/3-540-36117-0
isbn_softcover978-3-662-14612-5
isbn_ebook978-3-540-36117-6Series ISSN 1436-6002 Series E-ISSN 1616-8534
issn_series 1436-6002
copyrightSpringer-Verlag Berlin Heidelberg 2003
The information of publication is updating

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Enantioselective Synthesis by Lithiation Adjacent to Nitrogen and Electrophile Incorporation, with a single chiral ligand and diastereoselective and enantioselective conjugate additions with benzylic and allylic lithiation intermediates. The sequences are classified, where information is available, in terms of stereocontrol in the lithiation or substitution step.
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Book 2003n inspiration for future developments. Following an overview chapter summarising the key milestones, successive chapters, each written by leading experts in their field, critically survey all the major areas of progress..
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Enantioselective Conjugate Addition and 1,2-Addition to C=N of Organolithium Reagents,ine chemistry is also briefly presented. Sect. 2 summarizes the 1,2-additions to imines and imine congeners (hydrazones, oxime ethers, nitrones) using chiral auxiliaries and chiral ligands. We do not describe additions which use chiral auxiliary groups in carbonyl compounds.
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Enantioselective Addition of Organolithiums to C=O Groups and Ethers,es and ketones) or enantioselective cleavages of C-O units in strained ethers (i.e., epoxides and oxetanes) as well as in acetals. The achievement of high enantioselectivities is desirable and hence factors controlling these enantioselectivities are subjects of intensive research. Beneficial externa
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Enantioselective Conjugate Addition and 1,2-Addition to C=N of Organolithium Reagents, reactions of organolithium reagents constitutes a remarkable area of fundamental progresses in recent synthetic organic chemistry. The conjugate addition (or Michael reaction, 1,4-addition) and 1,2-addition to C= N double bonds are powerful methods for forming a carbon-carbon bond. This chapter rev
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