Titlebook: N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis; Catherine S.J. Cazin Book 2011 Springer Science+Business Media

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0920-4652 s in industrial processes, which is the first coverage of its kind, and brings a unique industrial context to this book..Included in this book:.Historical aspects of NHCs.Synthetic pathways to NHC precursors, f978-94-007-3370-1978-90-481-2866-2Series ISSN 0920-4652 Series E-ISSN 2215-180X

Bravura

,-Heterocyclic Carbene Complexes in Olefin Metathesis,s (CM) where non-cyclic partners are coupled through C–C double bond formation. These important transformations and variations on these themes mediated by second generation ruthenium complexes bearing a NHC ligand will be presented in the following sections.

AVID

,-Heterocyclic Carbene Complexes in Cyclisation Reactions,e cyclic products. The use of .-heterocyclic carbenes (NHCs) as ligands is a rapidly expanding field. As will be discussed in this chapter, these ligands have been used in conjunction with several metals in the synthesis of a wide range of carbocycles and heterocycles through cycloaddition reactions.

Bouquet

,-Heterocyclic Carbene Complexes in Polymerisation, Oligomerisation and Telomerisation Reactions, in the use of metal-NHC complexes in α-olefin polymerisation and oligomerisation, CO/olefin copolymerisation, atom-transfer radical polymerisation (ATRP) and diene telomerisation are discussed in subsequent sections.

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0920-4652 ix of young emerging researchers in the field of homogeneous.N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis. features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An expl

細(xì)絲

,-Heterocyclic Carbenes in Organocatalysis,The use of NHCs to participate in stereoselective reaction processes within each of these areas is also described, with an emphasis upon a mechanistic understanding of these processes given where appropriate.

Culmination

978-94-007-3370-1Springer Science+Business Media B.V. 2011

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