Titlebook: Electron Transfer Reactions in Organic Chemistry; Lennart Eberson Book 1987 Springer-Verlag Berlin Heidelberg 1987 catalysis.chemical reac

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Concepts and Definitions,ncept in an unambiguous way. Clearly we must have a stringent definition of electron transfer before we can discuss it. Definitions are however never trivial and ambiguity is attached to the concept of electron transfer, depending on both time and user. It is therefore necessary of digress for a whi

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Theories of Electron Transfer in Organic Chemistry,ative relationships, and phenomenologically derived principles. If any unifying trends can be discerned over the period since organic chemistry was born around 1860, it is the tenacity by which the concept of the chemical bond has been retained from the early theory of structure, and the strong emph

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How to Use the Marcus Theory,itious level one can simply look at the factors which influence the two variables in the parabolic term of the Marcus equation, Δ.°′ and λ, and qualitatively assess their influence on the feasibility of an ET step. Δ.°′ is a thermodynamic quantity and is accessible for experimental determination, wh

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Reactions Between Organic and Inorganic Non-metallic Species, not these processes are of a redox character, and hence fall within the scope of this book. This chapter will specifically deal with non-metallic inorganic redox reagents, among which we find most of the common electrophiles and nucleophiles, and discussed here because of their potential alternativ

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Electricity and Light Promoted ET,more detail. As pointed out in Chapter I, electrochemistry is the science of ET, as has been recognized for a long time, whereas the all-pervasive nature of photochemical ET has been generally appreciated only during the last 10–15 years. Also, the ET character of the converse process, emission of l

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