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Titlebook: Electron Transfer Reactions in Organic Chemistry; Lennart Eberson Book 1987 Springer-Verlag Berlin Heidelberg 1987 catalysis.chemical reac

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書(shū)目名稱Electron Transfer Reactions in Organic Chemistry
編輯Lennart Eberson
視頻videohttp://file.papertrans.cn/307/306171/306171.mp4
叢書(shū)名稱Reactivity and Structure: Concepts in Organic Chemistry
圖書(shū)封面Titlebook: Electron Transfer Reactions in Organic Chemistry;  Lennart Eberson Book 1987 Springer-Verlag Berlin Heidelberg 1987 catalysis.chemical reac
描述The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of electron transfer reactions (Marcus‘ and Pross-Shaik‘s approach) experimental diagnosis of electron transfer reactions, examples from inorganic/organic reactants and purely organic reactants, electro- and photochemical electron transfer, electron transfer catalyzed reactions, connections between electron transfer and polar mechanisms, and applications of electron transfer, such as electrosynthesis of organic chemicals, photochemical energy storage, conducting organic materials and chemiluminescence. The approach is new in so far as no comparable book has been published. The book will be of value to anyone interested in keeping track of developments in physical organic chemistry.
出版日期Book 1987
關(guān)鍵詞catalysis; chemical reaction; electrochemistry; inorganic chemistry; metals; organic chemistry; oxygen; syn
版次1
doihttps://doi.org/10.1007/978-3-642-72544-9
isbn_softcover978-3-642-72546-3
isbn_ebook978-3-642-72544-9Series ISSN 0341-2377
issn_series 0341-2377
copyrightSpringer-Verlag Berlin Heidelberg 1987
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Concepts and Definitions,ncept in an unambiguous way. Clearly we must have a stringent definition of electron transfer before we can discuss it. Definitions are however never trivial and ambiguity is attached to the concept of electron transfer, depending on both time and user. It is therefore necessary of digress for a whi
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Theories of Electron Transfer in Organic Chemistry,ative relationships, and phenomenologically derived principles. If any unifying trends can be discerned over the period since organic chemistry was born around 1860, it is the tenacity by which the concept of the chemical bond has been retained from the early theory of structure, and the strong emph
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How to Use the Marcus Theory,itious level one can simply look at the factors which influence the two variables in the parabolic term of the Marcus equation, Δ.°′ and λ, and qualitatively assess their influence on the feasibility of an ET step. Δ.°′ is a thermodynamic quantity and is accessible for experimental determination, wh
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Reactions Between Organic and Inorganic Non-metallic Species, not these processes are of a redox character, and hence fall within the scope of this book. This chapter will specifically deal with non-metallic inorganic redox reagents, among which we find most of the common electrophiles and nucleophiles, and discussed here because of their potential alternativ
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Electricity and Light Promoted ET,more detail. As pointed out in Chapter I, electrochemistry is the science of ET, as has been recognized for a long time, whereas the all-pervasive nature of photochemical ET has been generally appreciated only during the last 10–15 years. Also, the ET character of the converse process, emission of l
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