Titlebook: Chemisorption and Reactivity on Supported Clusters and Thin Films:; Towards an Understan Richard M. Lambert,Gianfranco Pacchioni Book 1997

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Supported Clusters, Structure, Reactivity and Microscopic Processes in Catalysis,of collective behavior in stoichiometric and catalytic reactions. In this sense, metal clusters occupy an intermediate position between molecular metal complexes(homogeneous catalysts) and bulky metals such as films and crystals (classic heterogeneous catalysts) in catalysis. Heterogeneous catalysts

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Co-Adsorption on Metal-Oxide Crystal Surfaces,rfaces (adsorption onto two different sites) and the strong reactivity towards CO. when submonolayer quantities of Na are preadsorbed.Valence-band data shows formation of carbonate. At low coverage the presence of a (CO.) complex suggests a 2CO. →CO. + CO reaction.

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Density Functional Cluster Calculations on Metal Deposition at Oxide Surfaces, the direct local electronic effect of oxide surfaces on supported metal particles. Despite this considerable technological importance very little is known about the microscopic nature of the interface between the surface of an oxide substrate, like MgO, SiO., Al.O., TiO., etc., and the contact meta

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Cluster Modelling of Oxide Surfaces: Structure, Adsorption and Reactivity,tinuously and rapidly increase in the future, and why it will probably become one of the most intensive human activities in the next century, is quite clear. In the past 30 years we have assisted to an exponential increase of the computing power. This has stimulated the creation of an adequate softw

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