Titlebook: Vibronic Interactions: Jahn-Teller Effect in Crystals and Molecules; Michael D. Kaplan,George O. Zimmerman Book 2001 Springer Science+Busi

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Androgen

犬儒主義者

Sum Rules for Jahn-Teller Reduction Factors,ere are fundamental sum-rule relations between first-order RFs that arise due to symmetry considerations. First-order sum rule results obtained recently for icosahedral systems are discussed and the ideas are extended to considerations of the corresponding second-order RFs.

RACE

形容詞詞尾

,Singlet Pairing Amongst Degenerate Electronic States: “Softening Bipolarons”, attributed to the singlets being formed amongst four-fold degenerate icosahedral orbitals. In particular, carriers in highly degenerate states can form a novel type of bipolaron, a “softening bipolaron.” Distinctive features of softening bipolarons result from singlets’ softening the symmetry-breaking vibrational modes to which they are coupled.

表兩個(gè)

LITHE

Orbital Ordering and Vibronic States in Manganese Perovskites,e 0.12 ≤ x ≤ 0.17. Three thermodynamically distinguishable ferromagnetic phases could be identified. Dynamic orbital disorder in vibronic phases and dynamic two-phase fluctuations are shown to suppress dramatically the thermal conductivity.

Laconic

Exchange Variation of Zero-Field Splitting in Polynuclear Clusters with High-Spin Ground State,ter ZFS parameters change value and sign under the variation of isotropic Heisenberg exchange and double exchange due to the exchange admixture of the excited states. The peculiarities of effective hyperfine constants A. of the [3FeZn-4S]. cluster with S.=5/2 were described in the exchange-resonance model with an admixture of the excited states.

SHRIK

Giant Negative Magnetoresistance and Strong Electron-Lattice Coupling in Amorphous Semiconductors wous alloys, where a similar explanation applies. The leading role of lattice polaron effect can be checked by measuring isotope effect upon substitution .Si → .Si, which should cause the temperature shift of the conductivity.

致敬

Jahn-Teller Effects in Transition Metal Oxides,eller effects give rise to a unique local atomic structure concomitant with an order-disorder transition. These studies illustrate how significantly the local structure can deviate from the average crystallographic structure and this can critically determine the properties of the solid.