Titlebook: Studies on Green Synthetic Reactions Based on Formic Acid from Biomass; Ming-Chen Fu Book 2020 The Editor(s) (if applicable) and The Autho

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Efficient Pd-Catalyzed Regio- and Stereoselective Carboxylation of Allylic Alcohols with Formic Acily effective for this transformation. The regio- and stereoconvergence of this reaction is ascribed to the thermodynamically favored isomerization of the allylic electrophile in the presence of the palladium catalyst.

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Nickel-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid Through Catalytic CO Recycling,nhydride, to achieve the hydrocarboxylation of various alkynes with formic acid with high selectivity and remarkable functional group compatibility, affording α, β-unsaturated carboxylic acids regio- and stereoselectively. Both terminal and internal alkynes are amenable substrates. A mechanism proce

interference

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Boron-Catalyzed ,-Methylation of Amines with Formic Acid,reagent with high efficiency and selectively. The method has a wide scope of substrates and good functional group compatibility. In addition, imines can be used for hydrogenative methylation conversion in one pot in the catalytic system.

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Book 2020s with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from

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