Titlebook: Stereodirected Synthesis with Organoboranes; Donald S. Matteson Book 1995 Springer-Verlag Berlin Heidelberg 1995 Aldehyde.Ketone.alkene.ca

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,Asymmetric Synthesis via (α-Haloalkyl)boronic Esters,99% enantiomeric excess. Several adjacent chiral centers and a wide variety of functional groups can be incorporated into the target compounds. The only restrictions are those imposed by high steric hindrance and reactive functionality.

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978-3-642-79711-8Springer-Verlag Berlin Heidelberg 1995

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Reactivity and Structure: Concepts in Organic Chemistryhttp://image.papertrans.cn/s/image/877364.jpg

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https://doi.org/10.1007/978-3-642-79709-5Aldehyde; Ketone; alkene; carbon; chirality; coupling reaction; metals; olefine; organometallic chemistry; ox

簡略

Alkenylboranes and Control of Olefinic Geometry, nucleofuge, such as halide, alkoxide, amino, or alkylthio. The other is via direct electrophilic replacement of boron from an alkenylborane. Many known examples in the first category derive the stereospecifically β-substituted borane from an alkenylborane, though there are significant exceptions that will be noted.