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Titlebook: State-to-State Dynamical Research in the F+H2 Reaction System; Zefeng Ren Book 2014 Springer-Verlag Berlin Heidelberg 2014 Born-Oppenheime

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書目名稱State-to-State Dynamical Research in the F+H2 Reaction System
編輯Zefeng Ren
視頻videohttp://file.papertrans.cn/877/876159/876159.mp4
概述Nominated as an outstanding contribution by Dalian Institute of Chemical Physics, Chinese Academy of Sciences.Introduces a new crossed molecular beam scattering apparatus with a high time-of-flight re
叢書名稱Springer Theses
圖書封面Titlebook: State-to-State Dynamical Research in the F+H2 Reaction System;  Zefeng Ren Book 2014 Springer-Verlag Berlin Heidelberg 2014 Born-Oppenheime
描述.This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of?F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA)?experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus?using a?hydrogen atom?Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address?the?above issues. The author also describes the observation of the?Feshbach resonance in?the?F+H2 reaction,?a?precise measurement of the differential cross section in?the?F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in?the?F+D2 reaction, and exploits the breakdown of BOA in the low collision energy..
出版日期Book 2014
關(guān)鍵詞Born-Oppenheimer Approximation; Crossed Molecular Beam Scattering; Differential Cross Section; Feschbac
版次1
doihttps://doi.org/10.1007/978-3-642-39756-1
isbn_softcover978-3-642-39755-4
isbn_ebook978-3-642-39756-1Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightSpringer-Verlag Berlin Heidelberg 2014
The information of publication is updating

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nt in the reconstruction of ancient plate boundaries. Present- day plate tectonic theories involve the generation and disposal of oceanic lithosphere, so that these ancient fragments of oceanic lithosphere can be used directly to reconstruct conditions within the ancient oceans. Since 1970, numerous
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Book 2014spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in?the?F+D2 reaction, and exploits the breakdown of BOA in the low collision energy..
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2190-5053 ular beam scattering apparatus with a high time-of-flight re.This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of?F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppe
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Introduction,bonds are broken and how the new bonds are formed. In the past few decades, molecular reaction dynamics is an important field of physical chemistry and chemical physics. Its main task is to study elementary chemical reaction processes on the atomic scale and femtosecond (even attosecond) time scale.
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,Dynamical Resonances in F?+?H2 Reactions,olved measurements. Using chemical laser and infrared light emitting, researchers found that the population of the product HF vibrational states is highly inverted. Crossed molecular beam studies of this system are the main work of Yuan Tseh Lee’s Nobel Prize in Chemistry in 1986. In this chapter, s
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