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Titlebook: Reactions of Coordinated Ligands; Volume 2 Paul S. Braterman Book 1989 Plenum Press, New York 1989 Coordination Chemistry.carbon.carbon dio

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書目名稱Reactions of Coordinated Ligands
副標(biāo)題Volume 2
編輯Paul S. Braterman
視頻videohttp://file.papertrans.cn/822/821860/821860.mp4
圖書封面Titlebook: Reactions of Coordinated Ligands; Volume 2 Paul S. Braterman Book 1989 Plenum Press, New York 1989 Coordination Chemistry.carbon.carbon dio
描述This, the second and final volume of Reactions of Coordinated Ligands, describes the chemistry of ligands bound through non-carbon atoms, and of coordinated carbon dioxide. As before, emphasis is on the underlying mechanisms, which provide a unity of understanding for superficially disparate processes. The wide range of topics covered illustrates well both the versatility and the usefulness of coordination chemistry in the controlled activation of ligands. Looking to the future, carbon dioxide is the feedstock of last resort. The homogeneous reduction of dinitrogen to ammonia now seems unlikely to replace the Haber process, but solution reactions also lead to more complex, varied, and valuable products. Nitrogen monoxide, a "non- innocent" ligand, impinges as pollutant and reagent. Its rich chemistry stems from its linked roles as three-electron donor, and as extremely powerful -acceptor. In the hydrolysis and condensation of complexed amides, esters etc. , metals act both as templates and as tunable and poly functional Lewis acids. Here the control of hydrophobic and steric interactions begins to model the subtle mechanisms of biological specificity. Finally, phosphorus and sulfur
出版日期Book 1989
關(guān)鍵詞Coordination Chemistry; carbon; carbon dioxide; lead; metals; polymer
版次1
doihttps://doi.org/10.1007/978-1-4613-0755-6
isbn_softcover978-1-4612-8066-8
isbn_ebook978-1-4613-0755-6
copyrightPlenum Press, New York 1989
The information of publication is updating

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Hydrolysis and Condensation Reactions of O- and N-Bound Ligands,icance of these reactions was fully recognized. A strong Jriving force has been the realization that some 30% of enzymes are metalloenzymes or require metal ions for activity. Many of the reactions dealt with in this chapter have been studied in an attempt to mimic the biochemical systems. Since Kro
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Reactions of Coordinated Phosphorus and Sulfur Ligands,red by this Chapter, viz: a comprehensive survey of P, As, Sb donor chemistry to mid-1972., diphosphine complexes., an early survey of transition metal complexes,. fluoralicyclic-P, As complexes,. phosphite, phosponite and amine-phosphine compounds,. Lewis base carbonyl complexes,. reactions of and
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d of coordinated carbon dioxide. As before, emphasis is on the underlying mechanisms, which provide a unity of understanding for superficially disparate processes. The wide range of topics covered illustrates well both the versatility and the usefulness of coordination chemistry in the controlled ac
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Reactions of Coordinated Dinitrogen and Related Species,ribe the recent advances in the studies of dinitrogen and related complexes with major emphasis on the reactions of coordinated dinitrogen in well characterized dinitrogen complexes. The reader is also referred to a number of reviews for chemical and biological studies on nitrogen fixation..
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Reactions of Coordinated Phosphorus and Sulfur Ligands,bene complexes,.P nmr spectra of complexes,. general structure. and structure of nitrosyl complexes,. reactions of coordinated pnictogens,. dioxygen complexes,. open-chain tetradentate. and tripod tetradentate chelates,. homogeneous hydrogenations. and general catalysis,.and a book which acts as a guide to the whole area..
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