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Titlebook: Oxidation Numbers and Oxidation States; Chr. Klixbüll J?rgensen Book 1969 Springer-Verlag Berlin Heidelberg 1969 Oxidation.Oxidationszahl.

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發(fā)表于 2025-3-21 19:20:35 | 只看該作者 |倒序瀏覽 |閱讀模式
書目名稱Oxidation Numbers and Oxidation States
編輯Chr. Klixbüll J?rgensen
視頻videohttp://file.papertrans.cn/706/705295/705295.mp4
叢書名稱Molekülverbindungen und Koordinationsverbindungen in Einzeldarstellungen
圖書封面Titlebook: Oxidation Numbers and Oxidation States;  Chr. Klixbüll J?rgensen Book 1969 Springer-Verlag Berlin Heidelberg 1969 Oxidation.Oxidationszahl.
描述The correlation of spectroscopic and chemical investigations in recent years has been highly beneficial of many reasons. Around 1950, no valid explanation was available of the colours of compounds of the five tran- sition groups. Later, it was possible to identify the excited levels with those expected for an electron configuration with adefinite number of electrons in the partly filled shell. I t is not generally recognized that this is equivalent to determining spectroscopic oxidation states related to the preponderant electron configuration and not to estimates of the fractional atomic charges. This brings in an entirely different type of description than the formal oxidation numbers used for characterizing compounds and reaction schemes. However, it must be realized that collectively oxidized ligands, formation of cluster-complexes and catenation may prevent the oxidation state from being well-defined. The writer would like to express his gratitude to many, but first of all to DR. CLAUS SCH?FFER, University of Copenhagen, who is the most efficient group-theoretical engineer known to the writer; his comments and discussions have been highly valuable. The writer‘s colleague, Pro-
出版日期Book 1969
關(guān)鍵詞Oxidation; Oxidationszahl; cluster; electron; electrons; metals; spectroscopy
版次1
doihttps://doi.org/10.1007/978-3-642-87758-2
isbn_softcover978-3-642-87760-5
isbn_ebook978-3-642-87758-2
copyrightSpringer-Verlag Berlin Heidelberg 1969
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沙發(fā)
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978-3-642-87760-5Springer-Verlag Berlin Heidelberg 1969
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Molekülverbindungen und Koordinationsverbindungen in Einzeldarstellungenhttp://image.papertrans.cn/o/image/705295.jpg
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Internal Transitions in Partly Filled Shells,and helium being far more common and the heavier elements not enriched as here. Thus, nearly all of the Fraunhofer lines of the solar spectrum are caused by elements lighter than zinc. The non-metallic elements (with exception of hydrogen) such as C, N, O, F, Ne, P, S, Cl, Ar,... show no strong abso
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Electron Transfer Spectra and Collectively Oxidized Ligands,inciple. Not only does no variation principle exist for energy differences, but the principle itself has entirely lost its backbone for any system containing more than ten electrons. Thus, the correlation energy, i.e. the difference between the full non-relativistic energy and the best Hartree-Fock
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Closed-Shell Systems, Hydrides and Back-Bonding,onation of monomeric formaldehyde H.CO. This rather extreme example illustrates a very important point about complexes having no low-lying excited levels: if there is any doubt about the oxidation state of the ligands, the acceptable values usually jump by two units with the result that the oxidatio
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