Titlebook: Organosilicon Derivatives of Phosphorus and Sulfur; S. N. Borisov,M. G. Voronkov,E. Ya. Lukevits Book 1971 Springer Science+Business Media

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Organosilicon Derivatives of Phosphorus and Sulfur978-1-4684-0727-3

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as follows from its subtitle "Derivatives of Inorganic Elements," this mono- graph could not cover the whole broad field of the chemistry of heteroorganic compounds of silicon. The main reason for this was above all the abundance and variety of original investigations of organosilicon derivatives of inorgani978-1-4684-0729-7978-1-4684-0727-3

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Organosilicon Derivatives of Phosphorus,When a mixture of trimethylchlorosilanes and anhydrous orthophosphoric acid (molar ratio 3: 1) is heated to boiling [62a] or when H.PO. is added gradually to trimethylchlorosilane [430, 525, 526], hydrogen chloride is liberated and tris(trimethylsilyl) phosphate is formed:

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Organosilicon Derivatives of Sulfur,The first compound of silicon containing the grouping Si—S—H was obtained in 1847 by passing a mixture of hydrogen sulfide and silicon tetrachloride through a red-hot porcelain tube. However, the substance formed was then taken to be C1.SiS [554–561].

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