Titlebook: Organometallic Pincer Chemistry; Gerard van Koten,David Milstein Book 2013 Springer-Verlag Berlin Heidelberg 2013 ECE-Type pincer.Multi-po

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Tuning of PCP Pincer Ligand Electronic and Steric Properties,s is presented. A review of the scope of syntheses, particularly in regard to the variation of phosphine PR. substituents, is followed by a general discussion of pincer steric variation, terdentate ligand conformations, and coordination geometries. Buried volume parameters, %V., provide a measure of

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Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence,nylpyridine. They are able to form a variety of highly luminescent complexes with platinum(II) and iridium(III). They can also be thought of as cyclometallating analogues of the NNN-coordinating ligand terpyridine. The introduction of the carbon atom can impart significant changes on the nature and

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Pincer Complexes as Catalysts in Organic Chemistry,ve formation of carbon–carbon, carbon–nitrogen, and carbon–metal (C–B, C–Si, and S–Sn) bonds, as well as transfer hydrogenation reactions. The described pincer-complex catalyzed processes are more efficient and more selective than the corresponding transformations catalyzed by metal salts and added

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Physical and Materials Applications of Pincer Complexes,e of intriguing physical and materials applications. The capacity for selective and directional metal–ligand coordination offers a tool for construction and function. Pincer complexes have been successfully used as a means for templating macrocycles, assembling metallodendrimers, functionalizing sur