書目名稱 | Organometallic Compounds | 副標題 | Volume Two: The Tran | 編輯 | G. E. Coates,M. L. H. Green,K. Wade | 視頻video | http://file.papertrans.cn/705/704509/704509.mp4 | 圖書封面 |  | 描述 | to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis- tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bon | 出版日期 | Book 1968 | 關鍵詞 | chromium; copper; gold; manganese; metals; molybdenum; nickel; olefine; organometallic chemistry; palladium; p | 版次 | 1 | doi | https://doi.org/10.1007/978-94-011-6893-9 | isbn_softcover | 978-94-011-6895-3 | isbn_ebook | 978-94-011-6893-9 | copyright | M. L. H. Green 1968 |
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