書(shū)目名稱 | New Synthetic Routes to Polyoxometalate Containing Ionic Liquids |
副標(biāo)題 | An Investigation of |
編輯 | Sven Herrmann |
視頻video | http://file.papertrans.cn/666/665788/665788.mp4 |
概述 | Publication in the field of natural sciences.Includes supplementary material: |
叢書(shū)名稱 | BestMasters |
圖書(shū)封面 |  |
描述 | In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and M??bauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials. |
出版日期 | Book 2015 |
關(guān)鍵詞 | EPR; FTOR; M??bauer spectroscopy; NMR; UV-Vis |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-658-08796-8 |
isbn_softcover | 978-3-658-08795-1 |
isbn_ebook | 978-3-658-08796-8Series ISSN 2625-3577 Series E-ISSN 2625-3615 |
issn_series | 2625-3577 |
copyright | Springer Fachmedien Wiesbaden 2015 |