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Titlebook: New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation; Rui Shang Book 2017 The Editor(s) (if app

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發(fā)表于 2025-3-21 18:50:58 | 只看該作者 |倒序?yàn)g覽 |閱讀模式
書目名稱New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation
編輯Rui Shang
視頻videohttp://file.papertrans.cn/665/664887/664887.mp4
概述Nominated as an outstanding PhD thesis by the University of Science and Technology of China.Highlights a series of highly efficient decarboxylative coupling reactions that will be of interest to synth
叢書名稱Springer Theses
圖書封面Titlebook: New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation;  Rui Shang Book 2017 The Editor(s) (if app
描述.This thesis presents the latest developments in new catalytic C–C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C–H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the iron catalyst with the help of density functional theory calculation.?.The thesis is divided into two parts, the first of which focuses on the development of a series of previously unexplored, inexpensive carboxylate salts as useful building blocks for the formation of various C–C bonds to access valuable chemicals. In turn, the second part is devoted to several new C–C bond formation methodologies using the most ubiquitous transition metal, iron, as a catalyst, and using the ubiquitous C–H bond as the coupling partner..
出版日期Book 2017
關(guān)鍵詞Metal catalysis; C-C bond formation; Decarboxylation; Palladium-catalyzed decarboxylative coupling; Carb
版次1
doihttps://doi.org/10.1007/978-981-10-3193-9
isbn_softcover978-981-10-9813-0
isbn_ebook978-981-10-3193-9Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightThe Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor
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沙發(fā)
發(fā)表于 2025-3-21 23:39:55 | 只看該作者
Book 2017decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C–H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the i
板凳
發(fā)表于 2025-3-22 02:02:23 | 只看該作者
地板
發(fā)表于 2025-3-22 07:48:26 | 只看該作者
Transition Metal-Catalyzed Decarboxylation and Decarboxylative Cross-Couplingslerance. In the present review, we summarize the various types of decarboxylative cross-coupling reactions catalyzed by different transition metal complexes. The scope and applications of these reactions are described. The challenges and opportunities in the field are discussed.
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發(fā)表于 2025-3-22 09:05:00 | 只看該作者
Palladium-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoester with Aryl and Alkenyl Halation shows that the decarboxylation on Pd(II) is the rate-determining step, with a transition state where Pd(II) has a five-coordination state. The calculated energy barrier of rate-determining step is about ~30?kcal/mol, which is in accordance with the optimized reaction temperature.
6#
發(fā)表于 2025-3-22 16:14:29 | 只看該作者
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發(fā)表于 2025-3-22 22:55:06 | 只看該作者
β-Arylation of Carboxamides Via Iron-Catalyzed C(sp3)–H Bond Activationial for the success of this reaction. This reaction shows selectivity for a primary C–H over a secondary one and is sensitive to steric factors on both the amide and the Grignard reagent. Various β-arylated aliphatic carboxamides can be readily prepared by using this method.
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發(fā)表于 2025-3-23 04:24:08 | 只看該作者
Springer Theseshttp://image.papertrans.cn/n/image/664887.jpg
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發(fā)表于 2025-3-23 06:39:31 | 只看該作者
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