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Titlebook: Magnetic Isotope Effect in Radical Reactions; An Introduction Kev M. Salikhov Book 1996 Springer-Verlag Wien 1996 chemical reaction.chemist

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發(fā)表于 2025-3-21 16:43:02 | 只看該作者 |倒序?yàn)g覽 |閱讀模式
書目名稱Magnetic Isotope Effect in Radical Reactions
副標(biāo)題An Introduction
編輯Kev M. Salikhov
視頻videohttp://file.papertrans.cn/622/621239/621239.mp4
圖書封面Titlebook: Magnetic Isotope Effect in Radical Reactions; An Introduction Kev M. Salikhov Book 1996 Springer-Verlag Wien 1996 chemical reaction.chemist
描述In the last two decades it was demonstrated that, in addition to masses and charges, magnetic moments of nuclei are able to influence remarkably chemical reactions. This book presents the physical background (both theoretical and experimental) of the magnetic isotope effects in radical reactions in solutions. Special attention has been paid to the quantitative interpretation of the available experimental data.This book will be useful for physicists, chemists and biologists employing the isotope effect in their investigations as well as for those involved in isotope separation and isotope enrichment projects. Additionally, the magnetic isotope effect appears to be important in geochemistry and cosmochemistry.The book can be recommended for postgraduates and senior undergraduate students.
出版日期Book 1996
關(guān)鍵詞chemical reaction; chemistry; geochemistry; isotope; ketones; kinetics; polymer
版次1
doihttps://doi.org/10.1007/978-3-7091-6569-0
isbn_softcover978-3-211-82784-0
isbn_ebook978-3-7091-6569-0
copyrightSpringer-Verlag Wien 1996
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發(fā)表于 2025-3-21 20:33:01 | 只看該作者
Main concepts of the theory of magnetic isotope effect, the applications of MIE. When analyzing experimental data, the observables should be expressed in terms of the effect of the isotope substitution on the recombination of intermediate radical pairs (RPs) or biradicals. Therefore, the chapter starts with a discussion of the relations between observab
板凳
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,Theoretical description of magnetic isotope effect in the Earth’s magnetic field,lectrons with the Earth’s field to singlet-triplet evolution of shortlived RPs can be ignored with reasonable accuracy. Typically, the hfi in free radicals is an order of magnitude larger than the Zeeman interaction with the Earth’s field. By virtue of this argument the results obtained for zero fie
地板
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Experimental evidences of magnetic isotope effect,ies of MIE were undertaken for the photolysis of dibenzyl ketone [15, 17, 20, 42, 51–53], as discussed in a review paper [6] and monograph [5] among others. The photolysis of DBK may serve as a model case to demonstrate the basic concepts and predictions of the MIE theory. Therefore, this chapter st
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978-3-211-82784-0Springer-Verlag Wien 1996
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