Titlebook: Infrared Spectroscopy of Molecular Clusters; An Introduction to I Martina Havenith Book 2002 Springer-Verlag Berlin Heidelberg 2002 cluster

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The CO Sideband Spectrometer,iation allows the generation of narrow (< 300 kHz) IR radiation which can be used for high-resolution spectroscopy of complexes. The overall experimental setup of a such a spectrometer is shown in Fig. 7.1. The spectrometer consists of several components, which will be described individually below.

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Book 2002urned more and more into an understanding of the weak, but important, int- molecular forces. New experimental techniques have been developed which have helped to gain more insight into this interesting topic. This book is intended as an introduction for graduate students who are familiar with the ma

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0081-3869 ludes supplementary material: This book is intended to give an introduction to intermolecular forces from an experimental point of view. Within the last 10 years the interest has turned more and more into an understanding of the weak, but important, int- molecular forces. New experimental techniques

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0081-3869 ly simple cases the theory car1 still fall short of an accurate description. For a long time (NH3)2 was considered as a prototype for hydrogen bo- ing. However, subsequent experime978-3-662-14648-4978-3-540-45457-1Series ISSN 0081-3869 Series E-ISSN 1615-0430

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Semiempirical Potentials,us different contributions in the previous chapter. If we summarize the various contributions obtained from second-order perturbation theory, we obtain the following equation: . where C. in the electrostatic term depends on the multipole moments of the monomer. For a noble-gas—molecule interaction t

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,Infrared Spectroscopy of Ar—CO,ese complexes the induction energy makes a considerable contribution to the overall binding energy, especially to the anisotropic part of the potential. The equilibrium structures of the complexes Ar—HBr, Ar—HCl and Ar—HF show a linear structure, corresponding to the maximum in the induction energy.

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