Titlebook: Hydrogen Bonding in Biological Structures; George A. Jeffrey,Wolfram Saenger Book 1991 Springer-Verlag Berlin Heidelberg 1991 DNA.Peptide.

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Effect of Hydrogen Bonding on Molecular Structurevalent bonds, depending upon the polarizability of the covalent bonding in the molecule. For this reason it is greatest in conjugated systems, where it is a structural manifestation of the ., discussed in Chap. 1.

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慢跑鞋

Purines and Pyrimidinesrivatives have been used most successfully in the investigations of biological processes and have found application in pharmacology [520, 521]. The same is true for the barbiturates, where the main emphasis is in pharmaceutical industry.

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Definitions and Conceptsydrogens attached to fluorine atoms and the weakest hydrogen bonds involve those attached to carbon atoms. It has long been known that with very electronegative donor and acceptor atoms, the hydrogen bond resembles a covalent bond, whereas, with weakly electronegative atoms, it is primarily electrostatic [42].

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Metrical Aspects of Three- and Four-Center Hydrogen BondsBecause in the (zwitterionic) amino acids there is a numerical imbalance between the (three) donor properties of the.and the (four) acceptor properties of the ?CO.., the proportion of three-center bonds is untypically high, amounting to almost three quarters of the total number of hydrogen bonds.