Titlebook: Homogeneous Catalysis with Metal Phosphine Complexes; Louis H. Pignolet Book 1983 Springer Science+Business Media New York 1983 catalysis.

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Polydentate Ligands and Their Effects on Catalysis,ine complexes display a tremendous range of coordination numbers, stereochemistries, catalytic properties, and selectivities. The effects can also be “fine-tuned” by purposeful variation of the steric and electronic effects of the substituent groups on phosphorus and from synthesis of polydentate phosphines..

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Cationic Rhodium and Iridium Complexes in Catalysis,. In this review, we will first survey the effects of net charget on the reactivity of metal complexes in general, before going on to the specific case of cationic complexes of rhodium and iridium in catalysis. We will not discuss work bearing on asymmetric hydrogenation, since this is covered in Chapter 3.

abduction

Hydrogenation Reactions of CO and CN Functions Using Rhodium Complexes,atalytic reduction of C==O and C==N double bonds. The present review summarizes the results in this area reported up until now. To give a more complete picture of the subject, some reports on iridium and ruthenium phosphine complex catalysts have been included as well.

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Decarbonylation Reactions Using Transition Metal Complexes,h several methods not utilizing transition metals are known. (including various deformylation reactions and thermal and photochemical decarbonylations), they are not general and not usually applicable under mild conditions where undesirable side reactions are minimized..

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Microcirculation Reviewhttp://image.papertrans.cn/h/image/428111.jpg

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Historical Introduction,nd the middle of the last century and their ability to combine with heavy metal salts noted almost immediately, but the application of their metal complexes to homogeneous catalysis came only after the lapse of about 100 years.