Titlebook: Helical Wormlike Chains in Polymer Solutions; Emeritus Hiromi Yamakawa Book 19971st edition Springer-Verlag Berlin Heidelberg 1997 DNA.dif

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,Chain Statistics — Helical Wormlike Chains, chains with different skeletal bond angles possess locally preferred helical conformations. Further, as anticipated in Chap. 3, it is impossible to assign local vectors and tensors to the KP chain unless they are parallel to and cylindrically symmetric about its contour, respectively.

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Excluded-Volume Effects, to the oligomer region where the excluded-volume effect disappears. Thus an extensive comparison of the new non-TP theory with experiment is made mainly using experimental data recently obtained for several flexible polymers. As for semiflexible polymers with small excluded volume, some remarks are

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Introduction,blication of the celebrated book by Flory [1] in 1953. In the next stage, activity was centered mainly in the study of dilute solution behavior of flexible polymers within the Flory framework which consists of that concept for the Gaussian chain and the universality of its . state without that effec

sorbitol

鍍金

,Chain Statistics — Wormlike Chains,ulation of the model and the theoretical methods which can also be applied to the statistical mechanics of the HW chain developed in the next chapter. Its static and transport properties are treated in later chapters as special cases of those of the HW chain. The unperturbed chain without excluded v

Fierce

柏樹

Equilibrium Properties,tion, scattering function, mean-square optical anisotropy, and mean-square electric dipole moment, of the unperturbed HW chain, including the KP wormlike chain as a special case, by an application of its chain statistics developed in Chap. 4. A comparison of theory with experiment is made with exper

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