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Titlebook: Gas-Phase Reactions; Kinetics and Mechani Victor N. Kondratiev,Evgeni? E. Nikitin Book 1981 Springer-Verlag Berlin, Heidelberg 1981 Absorpt

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31#
發(fā)表于 2025-3-26 21:35:52 | 只看該作者
Déjà-vu oder der nicht-spekul?re Restndependent treatment is based on the fact that the duration of molecular collisions (10. to 10. s) is typically much shorter than the average time between successive collisions (10. s under normal conditions). Thus, we can choose a time interval which is short compared to that between collisions, bu
32#
發(fā)表于 2025-3-27 04:58:20 | 只看該作者
https://doi.org/10.1007/978-3-030-90521-7r elementary chemical reactions and for relaxation processes. The relaxation rate constants must be allowed for explicitly only for processes occurring at a rate lower than or comparable with the reaction rates, i.e. for relaxations that can be considered to be incomplete in microscopic conversions
33#
發(fā)表于 2025-3-27 07:40:00 | 只看該作者
Frameworks, Libraries, and JavaScript,sidered as characteristic examples of such reactions. Defining unimolecular reactions in such a way, we disregard the question about the kinetics describing appropriate processes. It appears that the kinetics of these reactions (or the reaction order) depend on the extent to which perturbations, cau
34#
發(fā)表于 2025-3-27 12:19:35 | 只看該作者
35#
發(fā)表于 2025-3-27 15:54:41 | 只看該作者
https://doi.org/10.1007/978-3-030-45324-4e two cases differs. In electric discharge the mean energy of electrons is usually much lower than the ionization potential of molecules. Consequently, the ionization by electron impact in discharge, though needed for sustaining the discharge, to impart the electron energy to the gas, only makes up
36#
發(fā)表于 2025-3-27 19:33:39 | 只看該作者
37#
發(fā)表于 2025-3-27 23:19:33 | 只看該作者
General Kinetic Rules for Chemical Reactions, is usually measured by the number of moles of the given species per unit volume, i.e. by the value c = N/V mol/cm. (N is the number of moles, V is the volume in cm.) or by the number of molecules per unit volume (number density) n = cN. molecule/cm., where N. = 6.02 · 10. molecules per mole is the
38#
發(fā)表于 2025-3-28 05:06:41 | 只看該作者
39#
發(fā)表于 2025-3-28 08:45:36 | 只看該作者
40#
發(fā)表于 2025-3-28 12:55:30 | 只看該作者
Energy Exchange in Molecular Collisions,r elementary chemical reactions and for relaxation processes. The relaxation rate constants must be allowed for explicitly only for processes occurring at a rate lower than or comparable with the reaction rates, i.e. for relaxations that can be considered to be incomplete in microscopic conversions
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