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Titlebook: Gas Phase Chemical Reaction Systems; Experiments and Mode J. Wolfrum,H.-R. Volpp,J. Warnatz Conference proceedings 1996 Springer-Verlag Ber

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51#
發(fā)表于 2025-3-30 09:47:49 | 只看該作者
Hans-Dieter Lippert,Bernd-Rüdiger Kerne considered: The two triatom systems, namely F + H. and F + D., were treated twice employing two different potential energy surfaces. The calculations were carried out within the coupled states approximation. Two atom-triatom reactions were considered: the O + O. reaction, for which the calculation
52#
發(fā)表于 2025-3-30 15:23:07 | 只看該作者
Hans-Dieter Lippert,Bernd-Rüdiger Kern → H. + CN and H + N.O(ν.ν.ν.) → N. + OH, NH + NO. For H + HCN, we study the states (000), (004) and (302), and we find that C-H stretch excitation is much more effective than C-N stretch in lowering the reactive threshold energy and thus enhancing the rate constant. For H + N.O we study the states
53#
發(fā)表于 2025-3-30 19:35:50 | 只看該作者
Simulator-Training in RaffinerienUnder the unusual combination of conditions made possible within an impact heated cluster, the nominally four-center reactions can be made to proceed (on the computer) via the four-center mechanism as suggested by Bodenstein. It is even possible to achieve multi-center (> 4) reactions. The unique fe
54#
發(fā)表于 2025-3-30 22:03:32 | 只看該作者
https://doi.org/10.1007/978-3-531-90453-5 → HI + HI and its reverse HI + HI → H. + I.. Bodenstein measured the rates of the forward and reverse reactions, their equilibria, and their temperature dependence. He found second order kinetic expressions and an Arrhenius temperature dependence for the rate constants. He suggested several mechani
55#
發(fā)表于 2025-3-31 01:45:43 | 只看該作者
https://doi.org/10.1007/978-3-531-91730-6ularly considered because these results are important not only in theoretical chemical kinetics but also in practical applications. The work on five chemical reactions are reviewed in detail. These are: D + H., Cl + H., H + O., CH. + CH., and H + NO..
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