Titlebook: Enzymes as Catalysts in Organic Synthesis; M. P. Schneider Book 1986 D. Reidel Publishing Company, Dordrecht, Holland 1986 carbon.natural

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aesthetic

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Chivalrous

Chivalrous

Synthesis of Enantiomerically Pure Unnatural Compounds Via Non-Biomimetic Homoaldol Reactions-alkanones. After exchange of the cation by titanium or aluminium reagents, the addition proceeds with high. or . diastereoselectivity. Altogether, the new reagents provide the first more general method for stereocontrolled homoaldol reactions. A report on asymmetric homoaldol reactions, including results of several research groups, is also given.

Harness

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Synthesis of Chirally Labelled Substrates Using Enzymes acid. The latter compounds have been used to study the stereochemistry of some enzyme catalysed reactions. The enzymes glutamate pyruvate transaminase and β-methylaspartase have also been used synthetically in these studies.

shrill