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Titlebook: Energetics of Organometallic Species; J. A. Martinho Sim?es Book 1992 Springer Science+Business Media Dordrecht 1992 Silane.chemistry.comb

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書(shū)目名稱(chēng)Energetics of Organometallic Species
編輯J. A. Martinho Sim?es
視頻videohttp://file.papertrans.cn/310/309996/309996.mp4
叢書(shū)名稱(chēng)Nato Science Series C:
圖書(shū)封面Titlebook: Energetics of Organometallic Species; J. A. Martinho Sim?es Book 1992 Springer Science+Business Media Dordrecht 1992 Silane.chemistry.comb
描述An overview of modern organometallic thermochemistry, made by some of the most active scientists in the area, is offered in this book. The contents correspond to the seventeen lectures delivered at the NATO ASI Energetics of Organometallic Species (Curia, Portugal, September 1991), plus three other invited contributions from participants of that summer school. These papers reflect a variety of research interests, and discuss results obtained with several techniques. It is therefore considered appropriate to add a few preliminary words, attempting to bring some unity out of that diversity. In the first three chapters, results obtained by classical calorimetric methods are described. Modern organometallic thermochemistry started in Manchester, with Henry Skinner, and his pioneering work is briefly surveyed in the first chapter. The historical perspective is followed by a discussion of a very actual issue: the trends of stepwise bond dissociation enthalpies. Geoff Pilcher, another Manchester thermochemist, makes, in chapter 2, a comprehensive and authoritative survey of problems found in the most classical of thermochemical techniques - combustion calorimetr- applied to organometallic
出版日期Book 1992
關(guān)鍵詞Silane; chemistry; combustion; electrochemistry; metals; rhodium; transition metal
版次1
doihttps://doi.org/10.1007/978-94-011-2466-9
isbn_softcover978-94-010-5088-3
isbn_ebook978-94-011-2466-9Series ISSN 1389-2185
issn_series 1389-2185
copyrightSpringer Science+Business Media Dordrecht 1992
The information of publication is updating

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https://doi.org/10.1007/978-3-531-93450-1r laboratories. This includes the substitution of one- and two-electron donors in 17-electron cation radicals by two-electron donor nucleophiles. Kinetic parameters show that both types of processes appear to involve 19-electron intermediates or transition states. Also included are some rather unusu
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Historical Perspective of Organometallic Thermochemistry,ies in specific MX. compounds. The results indicate that these, D., D.…. D., vary considerably from the mean value,..The main reason for variability in the individual D values in MX. compounds is that the valence-state of the metal changes in moving along the series MX., MX., MX.…. M. In the case of
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Electrochemistry of some Organic and Organometallic Radicals and their Application in Thermochemicaon, there appears to be very little three electron bonding interaction between the phosphorous atoms of tetraaryldiphosphine radical cations. This results in a modest weakening of the P-P bond relative to the neutral species..The standard potentials, E°, for the oxidation of the tributyl- and triphe
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Bond Enthalpy Transferability - is it Achievable?, is a “weak” bond. This, in turn, is related to bond order: an interatomic bond of high order is both shorter and stronger than a bond of lower order between the same two elements. There is a lot of reliable experimental evidence to support these principles when elements of the first short period (n
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Guided Ion Beam Studies of the Energetics of Organometallic Species,gths of bonds in coordinatively saturated metal-ligand compounds. Initial studies that address the metal-ligand bond energies in such species more directly include measurements of the sequential bond energies of M(CO). . (x = 1–6), M(H.0). . (x = 1–4) and M(CH.). . (x = 1–4). Variations in these bon
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