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Titlebook: Endofullerenes; A New Family of Carb Takeshi Akasaka,Shigeru Nagase Book 2002 Springer Science+Business Media B.V. 2002 Ion.carbon.fulleren

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41#
發(fā)表于 2025-3-28 17:32:48 | 只看該作者
Group V Endohedral Fullerenes: N@C60, N@C70, and P@C60, atoms are almost freely suspended in these molecular cages and exhibit properties resembling those of ions in electromagnetic traps, i.e. sharp spectroscopic transitions and long life times. Since the fullerene shell can be easily manipulated, a large variety of different physical or chemical modifications can be realized.
42#
發(fā)表于 2025-3-28 19:34:40 | 只看該作者
Trimetallic Nitride Template (TNT) Endohedral Metallofullerenes,rchetypal representative of this new class is the stable endohedral metallofullerene, Sc.N@C. containing a triscandium nitride cluster encapsulated in an icosahedron (I.), C. cage. Other prominent TNT members are Sc.N@C. and Sc.N@C.. The former Sc.N@C. molecule represents an exception to the well known isolated pentagon rule (IPR).
43#
發(fā)表于 2025-3-29 01:24:29 | 只看該作者
Redox Properties and Purification of Endohedral Metallofullerenes, closed-shell soluble and open-shell soluble endohedral metallofullerenes are discussed here along with electrochemical methods for purification of both soluble and insoluble classes of metallofullerenes.
44#
發(fā)表于 2025-3-29 04:37:21 | 只看該作者
45#
發(fā)表于 2025-3-29 11:16:52 | 只看該作者
Putting Nonmetals into Fullerenes,n a beam of ions or fast atoms, or by generating the atom at high kinetic energy in a nuclear reaction. Several applications are described. NMR spectroscopy of .He inside is a general and useful probe for studying fullerene chemistry.
46#
發(fā)表于 2025-3-29 15:07:20 | 只看該作者
47#
發(fā)表于 2025-3-29 16:55:35 | 只看該作者
Collisional Production and Characterisation of Alkali Endohedral Fullerenes,ined in gas phase collision experiments, for the macroscopic production of alkali endohedral fullerenes using low energy ion implantation is described. The production conditions, the purification procedure, the stability and the characterisation of the isolated material are reviewed.
48#
發(fā)表于 2025-3-29 19:52:07 | 只看該作者
Structures and Electronic Properties of Endohedral Metallofullerenes; Theory and Experiment,mation mechanism and developing new routes to bulk production. Recent advances in the theoretical and experimental studies of structures and electronic properties are summarized for representative metallofullerenes as well as new metallofullerene members.
49#
發(fā)表于 2025-3-30 02:06:08 | 只看該作者
Trimetallic Nitride Template (TNT) Endohedral Metallofullerenes,ullerenes A.B.N@C. (n = 0–3, x = 34, 39, and 40) where A and B are metals (Group III and rare earths) that are formed in relatively high yields. The archetypal representative of this new class is the stable endohedral metallofullerene, Sc.N@C. containing a triscandium nitride cluster encapsulated in
50#
發(fā)表于 2025-3-30 06:04:24 | 只看該作者
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