Titlebook: Electronic and Vibronic Spectra of Transition Metal Complexes II; Hartmut Yersin Book 1997 Springer-Verlag Berlin Heidelberg 1997 Absorpti

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accomplishment

,Magnetic and spectroscopic properties of Os2(O2CR)4Cl2. Evidence for a 3(δ*π*) ground state, (O.CR is piv, butyrate, acetate) in fluid solutions and CsCl pellets have been examined, and polarized single crystal spectra have been measured for Os.piv.Cl.. The measurements have been extended to liquid helium temperature for solid samples. The temperature-dependent magnetic behavior and the pr

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Luminescence and absorption studies of transition metal ions in host crystals, pure crystals and suystals and surfaces. In the d. example, vanadium oxide on a SiO. substrate, the relation between the vibronic structure and the V = O bond length in the lowest excited electronic state and the reactivity toward CO is discussed. In the d. example, ReBr. and MnF. ions in single and mixed crystals, gro

Daily-Value

Angular overlap model applied to transition metal complexes and dN-ions in oxide host lattices,wn. The underlying theory is summarized, including recent extensions such as . mixing, misdirected valency, and non-additive π-contributions (Orgel effect), which may be important when chelate ligands with conjugated π-electrons are present. Experimental data obtained from optical spectra in absorpt

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Electronic and Vibronic Spectra of Transition Metal Complexes II

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0340-1022 theoretical and experimental studies for a deeper understanding of the electronic and vibronic properties of these compounds. In particular, an introduction into properties of spin sublevels of dd*, d?*, and ??* states is given, and a modern ligand field theory based on the Angular Overlap Model is