Titlebook: Electronic Transitions and the High Pressure Chemistry and Physics of Solids; H. G. Drickamer,C. W. Frank Book 1973 H. G. Drickamer and C.

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Phenomenological Description of Continuous Electronic Transitions,hand, some electronic transitions, including those in compounds of iron involving changes in spin state or oxidation state, occur continuously over a range of pressure. In fact, for the reduction of ferric to ferrous iron, one can frequently represent the conversion over a considerable range of pres

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Spin Changes in Iron Complexes,the interelectronic repulsion. It was also shown there that a ligand field of octahedral symmetry partially removes the degeneracy, giving a lower lying triplet of .(t.) symmetry and a higher energy doublet of .(e.) symmetry. We showed in Chapter 6 that for high spin complexes the ligand field incre

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