Titlebook: Electron Spin Resonance; Elementary Theory an John E. Wertz,James R. Bolton Book 1986 Chapman and Hall 1986 Exchange interaction.Hamiltonia

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Biological Applications of Electron Spin Resonance, appears to confirm earlier ideas that free radicals are involved as intermediates in metabolic processes. However, the question as to which free radicals are involved in a given metabolic process proved to be a much more difficult question to answer.

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Energy-level Splitting in Zero Magnetic Field. The Triplet State,electrons, a theorem due to Kramers? guarantees at least a twofold degeneracy which can only be removed by the application of a magnetic field. Thus, in principle, an ESR spectrum should be obtainable for any system with an odd number of electrons (. = 1/2, 3/2, 5/2, …).

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Hamilton College of Further Educationnalysis requires some experience. This chapter presents a large number of experimental spectra ranging from the simple to the complex. The reader is urged to consider each spectrum carefully and to understand its analysis before proceeding to the next. Section 4–7 presents a number of rules which should aid in the analysis of complex spectra.