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Titlebook: Electrochemistry on Liquid/Liquid Interfaces; P. Vanysek Book 1985 Springer-Verlag Berlin Heidelberg 1985 ITIES.Interfaces.Ion.Potentiosta

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發(fā)表于 2025-3-25 04:04:48 | 只看該作者
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發(fā)表于 2025-3-25 08:25:12 | 只看該作者
Theory,First we shall deal with the interface at equilibrium conditions. Figure 2 shows schematically a liquid-liquid interface at equilibrium as compared with similar situation at the boundary electrolyte — electrode.
23#
發(fā)表于 2025-3-25 12:10:11 | 只看該作者
Phase Transfer Catalysis,A basic difficulty in certain bimolecular reactions is that the nucleophilic reactant is salt-like and water soluble while the electrophilic substrate is organic and water insoluble. In this situation it is necessary to devise a method to bring these two compounds together.
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Lecture Notes in Chemistryhttp://image.papertrans.cn/e/image/305919.jpg
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https://doi.org/10.1007/978-3-662-60280-5nners similar to solid electrodes. Classical electrochemistry lends all the theoretical and experimental treatment of solid electrodes to the investigator in L/L electrochemistry in spite of the fact that transfer of ions across an immiscible electrolyte/electrolyte interface differs in several ways
27#
發(fā)表于 2025-3-26 07:48:44 | 只看該作者
Handbuch Empirische Organisationsforschungs of electrolytes is similar to that of metal/electrolyte or semiconductor/electrolyte interface. An interface, which is a site of a potential difference, must exhibit some type of a potential gradient across itself. The electrolyte side of a metal/electrolyte interface is described as being a site
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發(fā)表于 2025-3-26 09:14:12 | 只看該作者
Handbuch Energieeffizienz im Quartierange of ions responsible for determination of the Nernst potential takes place in a manner completely analogous to the situation typical for metal electrode immersed in solution of potential determining ions. The exchange of ions at equilibrium can be characterized by an ., a quantity which is not i
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