Titlebook: Electrified Interfaces in Physics, Chemistry and Biology; R. Guidelli Book 1992 Springer Science+Business Media Dordrecht 1992 biology.che

整頓

https://doi.org/10.1007/978-3-319-26782-1onstants can be corrected for electrostatic effects by considering the Gouy Chapman theory. The surface reactivity depends on surface structure (surface speciation). A general rate law on the surface controlled dissolution of oxide minerals can be derived by combining concepts of surface coordinatio

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An Overview of Electrified Interfaces,s, in semiconductors and in redox systems is provided. Experimentally accessible quantities such as work function, contact potential and absolute electrode potential are examined. Interfacial charge distributions due both to coulombic forces and to specific noncoulombic forces are described. The met

Fibrin

Structure and Electronic Properties of Metal Surfaces,e surface are different in almost every respect from those in the bulk of the same material. Crystallographically surfaces are relaxed or even reconstructed. As a consequence of this geometrical rearrangement also the electronical properties at the surface are different from the bulk properties. For

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Ab-Initio Molecular Dynamics: Selected Applications to Disordered Systems and Surfaces,ade it possible to perform molecular dynamics simulations with pa,rameter-free potentials: Interatomic forces due to the quantllm electronic system are derived from first-principles within the framewolk of density functional theory. This new scheme has permitted the solution of problems for real mat

SEVER

The Problem of Schottky Barrier,hysical reasons for the formation of a Schottky barrier. Among them the Schottky model, the interface states model, the metal-induced gap states (MIGS) model and the defect model will be reviewed. Experimental methods for the determination of the Schottky barrier will be presented, including a short

留戀

The Semiconductor/Electrolyte Interface,ues that are used to characterise single crystal semiconductors and oxide coated metals. These methods include photocurrent spectroscopy, non steady-state photocurrent techniques and in-situ infrared spectroscopy.

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貨物

Discrete

Phenomenological Approach to Metal/Electrolyte Interfaces,e past twenty years. In particular, the behaviour of .-metals (Au,Ag,Cu) is discussed in the context of the group of .-metals. The potential of zero charge vs work function plot shows that .-metals cannot be gathered in a single group. The parameter ΔX. derived from the plot. and measuring the pertu

隨意

The Application of Scanning Tunneling Microscopy to Electrochemistry, outlines the basic principles of STM and the special experimental considerations for operation in electrolyte. Four case studies, performed at our laboratories, are discussed, with the aim of providing an insight into the valuable information which can be obtained by using this technique.