Titlebook: Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance; Janne Marie Soetbeer Book 2016 The Editor(s) (if appl

植物學(xué)

https://doi.org/10.1007/978-3-662-08690-2n electron spin pairs introduced in biomolecules by site-directed spin labelling (SDSL) in the nanometer range. The obtainable distance range and sensitivity of the DEER experiment strongly depends on the transverse relaxation of the electron spin as this determines the maximal available dipolar evolution time in the DEER experiment.

NAUT

Introduction and Theory,n electron spin pairs introduced in biomolecules by site-directed spin labelling (SDSL) in the nanometer range. The obtainable distance range and sensitivity of the DEER experiment strongly depends on the transverse relaxation of the electron spin as this determines the maximal available dipolar evolution time in the DEER experiment.

Pantry

https://doi.org/10.1007/978-3-662-08690-2n electron spin pairs introduced in biomolecules by site-directed spin labelling (SDSL) in the nanometer range. The obtainable distance range and sensitivity of the DEER experiment strongly depends on the transverse relaxation of the electron spin as this determines the maximal available dipolar evo

木訥

拋射物

Janne Marie SoetbeerStudy in Natural Science.Includes supplementary material:

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APEX

978-3-658-14669-6The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Fachmedien Wies

倫理學(xué)

https://doi.org/10.1007/978-3-662-08690-2Model systems were chosen to mimic typical DEER application scenarios for which the relaxation behaviour of the nitroxide spin in the different spin environments (i.e. protonated, partly or completely deuterated solvent) was studied.

語源學(xué)

https://doi.org/10.1007/978-3-662-08690-2Relaxation measurements for all samples were carried out. The resulting relaxation traces for TEMPOL, T4 Lysozyme, WALP23 and MS107 at Q-band frequencies were normalised by the maximum signal intensity of the 4-DEER trace. This normalisation allows to compare the refocusing scheme performance relative to the 4-DEER setup as a function of time.