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Titlebook: Design and Precise Synthesis of Thermoresponsive Polyacrylamides; Keita Fuchise Book 2014 Springer Japan 2014 Click Reaction.Group Transfe

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書目名稱Design and Precise Synthesis of Thermoresponsive Polyacrylamides
編輯Keita Fuchise
視頻videohttp://file.papertrans.cn/269/268596/268596.mp4
概述Nominated by Hokkaido University as an outstanding Ph.D. thesis.Explains easy and versatile methods to control the thermoresponsive properties of polyacrylamides.Furnishes useful results for further d
叢書名稱Springer Theses
圖書封面Titlebook: Design and Precise Synthesis of Thermoresponsive Polyacrylamides;  Keita Fuchise Book 2014 Springer Japan 2014 Click Reaction.Group Transfe
描述.In this thesis, the author describes versatile and easy-to-use methods to control the properties of thermoresponsive polyacrylamides by developing novel synthetic methods for end-functionalized poly(.N.-isopropylacrylamide) (PNIPAM) and block copolymers of poly(.N,N.-diethylacrylamide) (PDEAA). The synthesis of various urea end-functionalized PNIPAMs was achieved by the atom transfer radical polymerization (ATRP) and the click reaction. The phase transition temperature of PNIPAM in water was controlled depending on the strength of the hydrogen bonding of the urea groups introduced at the chain end of the polymer. Novel living polymerization methods for .N.,.N.-dimethylacrylamide and .N.,.N.-diethylacrylamide were developed by group transfer polymerization (GTP) using a strong Br?nsted acid as a precatalyst and an amino silyl enolate as an initiator. This process enabled the precise synthesis of PDEAA and its block copolymers—namely, thermoresponsive amphiphilic block copolymers and double-hydrophilic block copolymers..
出版日期Book 2014
關(guān)鍵詞Click Reaction; Group Transfer Polymerization (GTP); Organocatalysts; Poly(N,N-diethylacrylamide) (PDEA
版次1
doihttps://doi.org/10.1007/978-4-431-55046-4
isbn_softcover978-4-431-56403-4
isbn_ebook978-4-431-55046-4Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightSpringer Japan 2014
The information of publication is updating

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Yuri Gil Dantas,Tobias Hamann,Heiko Mantelthe copper-catalyzed azide-alkyne cycloaddition as well as the control of the thermoresponsive properties of PNIPAM by changing the hydrogen bonding ability of the terminal urea groups.? The phase transition temperature of the obtained polymers varied depending on the hydrogen bonding ability of the
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Network Anomaly Detection on IDS Stream Logs, one of the strong Br?nsted acids, which proceeded in a living fashion for the synthesis of polyacrylamides with well-defined structures.? The Tf.NH-promoted GTP of DMAA initiated by (.)-1-(dimethylamino)-1-trimethylsiloxy-1-propene ((.)-DATP), an amino silyl enolate, at 0 °C homogeneously proceede
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Book 2014r polymerization (GTP) using a strong Br?nsted acid as a precatalyst and an amino silyl enolate as an initiator. This process enabled the precise synthesis of PDEAA and its block copolymers—namely, thermoresponsive amphiphilic block copolymers and double-hydrophilic block copolymers..
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