Titlebook: Cyclometalation Reactions; Five-Membered Ring P Iwao Omae Book 2014 Springer Japan 2014 Agostic Interaction.C-H Activation.C-H Functionaliz

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Concluding Remarks,, O, or S, to a metal atom. This is followed by γ-C–H agostic interactions, C–H activation, and the chelate effect in this order (Eq. (6.7)). A recent report entitled “Chelation-Assisted Reactions (Eqs. (6.42)–(6.51))” provides evidence that the chelate effect is a strong activation source for cyclometalation reactions.

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https://doi.org/10.1007/978-4-431-54604-7Agostic Interaction; C-H Activation; C-H Functionalization; C-X Activation; Chelate Effect; Coordination

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Iwao OmaeFirst book-length and comprehensive treatment of cyclometalation reactions.Explains the development of research in cyclometalation reactions since the 1960s.Provides many equations and schemes of reac

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https://doi.org/10.1007/978-3-662-49916-0Applications of five-membered ring products as catalysts in cyclometalation reactions include chiral reactions, metathesis reactions, cross-coupling reactions, and polymerization reactions. Other reactions include reductions, Michael addition reactions, dehydrogenations, Diels–Alder reactions, and hydrogenations.

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Ethische Fragen in der NeuroradiologieApplications of five-membered ring products in cyclometalation reactions for other purposes include organic electronic devices, pharmaceuticals, dye-sensitized solar cells, carbon dioxide utilizations, sensors, dendrimers, liquid crystals, resolving agents, and photosensitizers for hydrogen production.

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