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Titlebook: Collision- and Interaction-Induced Spectroscopy; G. C. Tabisz,M. N. Neuman Book 1995 Springer Science+Business Media Dordrecht 1995 Planet

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書目名稱Collision- and Interaction-Induced Spectroscopy
編輯G. C. Tabisz,M. N. Neuman
視頻videohttp://file.papertrans.cn/230/229618/229618.mp4
叢書名稱Nato Science Series C:
圖書封面Titlebook: Collision- and Interaction-Induced Spectroscopy;  G. C. Tabisz,M. N. Neuman Book 1995 Springer Science+Business Media Dordrecht 1995 Planet
描述Collision-or interaction-induced spectroscopy refers to radiative transitions, which are forbidden in free atoms or molecules, but which occur in clusters of interacting atoms or molecules. The most common phenomena are induced absorption, in the infrared region, and induced light scattering, which involves inelastic scattering of visible laser light. The particle interactions giving rise to the necessary induced dipole moments and polarizabilities are modelled at long range by multipole expansions; at short range, electron overlap and exchange mechanisms come into play. Information on atomic and molecular interactions and dynamics in dense media on a picosecond timescale may be drawn from the spectra. Collision-induced absorption in the infrared was discovered at the University of Toronto in 1949 by Crawford, Welsh and Locke who studied liquid O and N. Through the 1950s and 1960s, 2 2 experimental elucidation of the phenomenon, particularly in gases, continued and theoretical underpinnings were established. In the late 1960s, the related phenomenon of collision-induced light scattering was first observed in compressed inert gases. In 1978, an ‘Enrico Fermi‘ Summer School was held
出版日期Book 1995
關(guān)鍵詞Planet; astrophysics; collision; scattering; spectra; spectroscopy
版次1
doihttps://doi.org/10.1007/978-94-011-0183-7
isbn_softcover978-94-010-4082-2
isbn_ebook978-94-011-0183-7Series ISSN 1389-2185
issn_series 1389-2185
copyrightSpringer Science+Business Media Dordrecht 1995
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Fragetechnik und aktives Zuh?renn corresponding to the depolarized interaction-induced light scattering. The short-time behavior of this function is numerically analyzed. The results compare well with molecular dynamics simulations on the time scale up to five mean free times between collisions. Within the proposed scheme the expression for the integrated intensity is exact.
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Sicheres Auftreten im internationalen Umfeldarly with the relative displacement between neighbouring units. This model is used to generate numerical bandshape calculations for the X-H absorption spectrum. At high T(>60 K), the model reproduces the temperature dependence of the O-H bandwidth for crystalline methanol. The low-T behaviour remains problematic.
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https://doi.org/10.1007/978-3-8349-9222-2l information that can be extracted is limited, but it may well be the best source of such information currently obtainable. We discuss methods of evaluating this intensity, as well as its significance for structural studies.
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https://doi.org/10.1007/978-3-8349-9222-2S. The shape of the spectrum depends on both the endohedral potential governing this motion, and on the form of the induced dipole or polarizability. We discuss various methods for the calculation of these quantities. Induced bands of these species are unusual in that they are discrete, not continuous; they may also be very intense.
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Ternary Effects in Far IR Absorption in the Gas Phaseas molecules and in pure rare gases. Very similar methods were also used to calculate the binary correlation function for a mixture of quadrupolar molecules with rare gas molecules when the anisotropy in the interaction potential is taken explicitly into account.
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