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Titlebook: Collision Theory and Statistical Theory of Chemical Reactions; Stefan G. Christov Textbook 1980 Springer-Verlag Berlin Heidelberg 1980 Act

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發(fā)表于 2025-3-21 18:38:49 | 只看該作者 |倒序瀏覽 |閱讀模式
書目名稱Collision Theory and Statistical Theory of Chemical Reactions
編輯Stefan G. Christov
視頻videohttp://file.papertrans.cn/230/229615/229615.mp4
叢書名稱Lecture Notes in Chemistry
圖書封面Titlebook: Collision Theory and Statistical Theory of Chemical Reactions;  Stefan G. Christov Textbook 1980 Springer-Verlag Berlin Heidelberg 1980 Act
描述Since the discovery of quantum mechanics,more than fifty years ago,the theory of chemical reactivity has taken the first steps of its development. The knowledge of the electronic structure and the properties of atoms and molecules is the basis for an un- derstanding of their interactions in the elementary act of any chemical process. The increasing information in this field during the last decades has stimulated the elaboration of the methods for evaluating the potential energy of the reacting systems as well as the creation of new methods for calculation of reaction probabili- ties (or cross sections) and rate constants. An exact solution to these fundamental problems of theoretical chemistry based on quan- tum mechanics and statistical physics, however, is still impossible even for the simplest chemical reactions. Therefore,different ap- proximations have to be used in order to simplify one or the other side of the problem. At present, the basic approach in the theory of chemical reactivity consists in separating the motions of electrons and nu- clei by making use of the Born-Oppenheimer adiabatic approximation to obtain electronic energy as an effective potential for nuclear mot
出版日期Textbook 1980
關(guān)鍵詞Activation energy; Chemische Reaktion; Cross section; Quantenchemie; Reactions; chemistry; energy; heat; inf
版次1
doihttps://doi.org/10.1007/978-3-642-93142-0
isbn_softcover978-3-540-10012-6
isbn_ebook978-3-642-93142-0Series ISSN 0342-4901 Series E-ISSN 2192-6603
issn_series 0342-4901
copyrightSpringer-Verlag Berlin Heidelberg 1980
The information of publication is updating

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沙發(fā)
發(fā)表于 2025-3-22 00:14:33 | 只看該作者
https://doi.org/10.1007/978-3-662-63986-3e system means taking into account the possibility of non-adiabatic transitions from one to another potential energy surface. This is still an unsolved problem of theoretical chemistry which is open for discussion.
板凳
發(fā)表于 2025-3-22 01:30:28 | 只看該作者
地板
發(fā)表于 2025-3-22 05:10:30 | 只看該作者
Concluding Remarks,e system means taking into account the possibility of non-adiabatic transitions from one to another potential energy surface. This is still an unsolved problem of theoretical chemistry which is open for discussion.
5#
發(fā)表于 2025-3-22 09:12:18 | 只看該作者
0342-4901 pment. The knowledge of the electronic structure and the properties of atoms and molecules is the basis for an un- derstanding of their interactions in the elementary act of any chemical process. The increasing information in this field during the last decades has stimulated the elaboration of the m
6#
發(fā)表于 2025-3-22 14:38:43 | 只看該作者
Textbook 1980 knowledge of the electronic structure and the properties of atoms and molecules is the basis for an un- derstanding of their interactions in the elementary act of any chemical process. The increasing information in this field during the last decades has stimulated the elaboration of the methods for
7#
發(fā)表于 2025-3-22 19:58:32 | 只看該作者
Sicheres Auftreten in Social Mediaations of A and B assumed to be one molecule per unit volume), T is the absolute temperature and k is the Boltzmann constant. This expression has the form of the empirical Arrhenius equation. where K and E. are constants which can be determined experimentally in a relatively restricted temperature range.
8#
發(fā)表于 2025-3-22 23:23:35 | 只看該作者
Historical Introduction,ations of A and B assumed to be one molecule per unit volume), T is the absolute temperature and k is the Boltzmann constant. This expression has the form of the empirical Arrhenius equation. where K and E. are constants which can be determined experimentally in a relatively restricted temperature range.
9#
發(fā)表于 2025-3-23 04:43:51 | 只看該作者
Sicheres Auftreten in Social Mediaecades ago by LEWIS (1918), HERZFELD (1919), POLA-NYI (1920), HINSHELWOOD (1937) a.o./2/. For a simple bimolecular reaction of the type . this theory admits that the reaction occurs if the kinetic energy of the relative translation of the colliding molecules (or atoms) A and B is greater than some c
10#
發(fā)表于 2025-3-23 06:56:57 | 只看該作者
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