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Titlebook: Chiral Diazaligands for Asymmetric Synthesis; Marc Lemaire,Pierre Mangeney Book 2005 Springer-Verlag Berlin Heidelberg 2005 Organometallic

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發(fā)表于 2025-3-21 16:43:31 | 只看該作者 |倒序瀏覽 |閱讀模式
書目名稱Chiral Diazaligands for Asymmetric Synthesis
編輯Marc Lemaire,Pierre Mangeney
視頻videohttp://file.papertrans.cn/226/225946/225946.mp4
概述Provides the broad scientific readership with comprehensive summary and critical overview of a topic in organometallic chemistry.Research in this rapidly developing transdisciplinary field is having p
叢書名稱Topics in Organometallic Chemistry
圖書封面Titlebook: Chiral Diazaligands for Asymmetric Synthesis;  Marc Lemaire,Pierre Mangeney Book 2005 Springer-Verlag Berlin Heidelberg 2005 Organometallic
描述.The use of phosphine derivatives has historically induced the tremendous development of catalysis (both non-asymmetric and asymmetric). Although the chemistry of amines is more documented, the use of nitrogen-containing ligands only appeared recently. Nevertheless, during the last ten years, the results describing chiral diamine preparations and their uses in asymmetric catalysis and synthesis are increasing faster than their phosphorus counterparts. The reader will find in this volume the most recent methods for the synthesis of chiral diamines as well as their applications in asymmetric catalysis of CC bond formation. Particular attention will be given to spartein and derivatives of such diamines. Recently, the particular properties and the chemistry of amines allowed to obtain catalysts easy to separate and recycle and new types of ligands such as diaminocarbenes, ureas and thioureas. Finally, the complexing properties of some diamines allowed the formation of complexes with chirality "at the metal " which is of major theoretical interest and presents numerous potential applications..
出版日期Book 2005
關(guān)鍵詞Organometallic chemistry; catalysis; medicinal chemistry; metals
版次1
doihttps://doi.org/10.1007/b105252
isbn_softcover978-3-642-06538-5
isbn_ebook978-3-540-31442-4Series ISSN 1436-6002 Series E-ISSN 1616-8534
issn_series 1436-6002
copyrightSpringer-Verlag Berlin Heidelberg 2005
The information of publication is updating

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發(fā)表于 2025-3-21 21:35:03 | 只看該作者
1436-6002 ypes of ligands such as diaminocarbenes, ureas and thioureas. Finally, the complexing properties of some diamines allowed the formation of complexes with chirality "at the metal " which is of major theoretical interest and presents numerous potential applications..978-3-642-06538-5978-3-540-31442-4Series ISSN 1436-6002 Series E-ISSN 1616-8534
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Supply and Demand, Considered Together,rdinating site located at close proximity to the stereogenic sulfur atom, have also proven their efficiency as copper ligands for these asymmetric cycloadditions. Other precursors for this Lewis acid-catalyzed transformation have been described (e.g., zinc salts, ruthenium derivatives, or rare earth
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Book 2005. Finally, the complexing properties of some diamines allowed the formation of complexes with chirality "at the metal " which is of major theoretical interest and presents numerous potential applications..
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Supply and Demand, Considered Together,oline) structures have been the most studied, probably due to their straightforward synthesis from the chiral pool, their easy handling, and their high stability. Efficient methods have been reported for the intermolecular cyclopropanation of olefins (mainly styrene derivatives) with alkyldiazoaceta
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Supply and Demand, Considered Separately,erogeneous catalysts with, in principle, less influence of the support on the conformational preferences of the catalytic complex. In this review the different possibilities for immobilization without forming a covalent bond between the chiral diazaligand and the support, which can be either solid o
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