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Titlebook: Chemistry in Action: Making Molecular Movies with Ultrafast Electron Diffraction and Data Science; Lai Chung Liu Book 2020 Springer Nature

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發(fā)表于 2025-3-21 16:20:24 | 只看該作者 |倒序?yàn)g覽 |閱讀模式
書目名稱Chemistry in Action: Making Molecular Movies with Ultrafast Electron Diffraction and Data Science
編輯Lai Chung Liu
視頻videohttp://file.papertrans.cn/225/224840/224840.mp4
概述Nominated as an outstanding PhD thesis by the University of Toronto.Includes an accessible introduction to transient absorption spectroscopy, ultrafast electron diffraction, and related data science t
叢書名稱Springer Theses
圖書封面Titlebook: Chemistry in Action: Making Molecular Movies with Ultrafast Electron Diffraction and Data Science;  Lai Chung Liu Book 2020 Springer Nature
描述.The thesis provides the necessary experimental and analytical tools to unambiguously observe the atomically resolved chemical reactions. A great challenge of modern science has been to directly observe atomic motions during?structural transitions, and while this was first achieved through a major advance in electron source brightness, the information content was still limited and new methods for image reconstruction using femtosecond electron diffraction methods were needed. One particular challenge lay in reconciling the innumerable possible nuclear configurations with the observation of chemical reaction mechanisms that reproducibly give the same kind of chemistry for large classes of molecules. The author shows that there is a simple solution that occurs during barrier crossing in which the highly anharmonic potential at that point in nuclear rearrangements couples high- and low-frequency vibrational modes to give highly localized nuclear motions, reducing hundreds ofpotential degrees of freedom to just a few key modes. Specific examples are given in this thesis, including two photoinduced phase transitions in an organic system, a ring closure reaction, and two direct observati
出版日期Book 2020
關(guān)鍵詞ultrafast dynamics; ultrafast electron diffraction; molecular movie; transient absorption spectroscopy;
版次1
doihttps://doi.org/10.1007/978-3-030-54851-3
isbn_softcover978-3-030-54853-7
isbn_ebook978-3-030-54851-3Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightSpringer Nature Switzerland AG 2020
The information of publication is updating

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發(fā)表于 2025-3-21 23:44:04 | 只看該作者
https://doi.org/10.1007/978-3-030-91424-0istry 1963–1970, Amsterdam, Elsevier, 1972) were awarded to crystallographers John C. Kendrew (1917–1997), Max F. Perutz (1914–2002), and Dorothy C. Hodgkin (1910–1994) for their work in determining for the first time the 3D structure of several important macromolecules.
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發(fā)表于 2025-3-22 04:00:01 | 只看該作者
地板
發(fā)表于 2025-3-22 05:19:34 | 只看該作者
https://doi.org/10.1007/978-3-030-54851-3ultrafast dynamics; ultrafast electron diffraction; molecular movie; transient absorption spectroscopy;
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發(fā)表于 2025-3-22 20:39:33 | 只看該作者
Muhammad Rana,Quazi Mamun,Rafiqul IslamThe focus of this chapter is a study that uses UED to probe the atomic motions that take place during the ‘photocyclization’ or photoinduced ring-closing reaction of the molecule 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)perfluorocyclopentene, herein abbreviated to PFC.
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發(fā)表于 2025-3-22 23:53:36 | 只看該作者
Muhammad Rana,Quazi Mamun,Rafiqul IslamSome transition-metal complexes can change spin states under certain perturbation of their environment. This process is called spin crossover (SCO) and this chapter is focused on its role in the light-induced dynamics of two iron(II) compounds: [Fe.(bpy).](PF.). and [Fe.(PM-AzA).(NCS).], abbreviated herein to BPY and AZA respectively.
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發(fā)表于 2025-3-23 04:51:06 | 只看該作者
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發(fā)表于 2025-3-23 09:16:29 | 只看該作者
Ultrafast Structural Dynamics of (EDO-TTF)2X,In this chapter, I will present two studies on the photoinduced structural dynamics of the crystalline material (EDO-TTF).X. For context, a general overview of this molecular system will be given. This is followed by a description of the experimental procedure and a discussion of the results from the studies.
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