Titlebook: Catalytic Activation and Functionalisation of Light Alkanes; Advances and Challen Eric G. Derouane,Jerzy Haber,Michel Guisnet Book 1998 Spr

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書目名稱Catalytic Activation and Functionalisation of Light Alkanes影響因子(影響力)




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The Concepts of ‘Civilisation’ and ‘Culture’d tungsten carbides possess a . surface that catalyzes both dehydrogenation and carbenium ion reactions typically occurring on reforming catalysts [3]. These findings are not unique to tungsten carbides and depend on the preparation of materials.

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The Effect of Acid Sites in Skeletal Isomerization of N-Butenes over Ferrierites and Coalpo-11 at least 48 hrs. This is a result, besides very narrow channels, of cooperative effect of weakly acidic both P-OH groups and Co. ?Lewis sites. When P-OH groups were completely removed by calcination, skeletal isomerization selectively proceeds only on Co. sites.

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Oxidative Dehydrogenation of Propane on Large-Pore Zeolitesd by the faujasite matrix significantly increase the selectivity to propene [2]. Preliminary results on zeolite Beta modified with Ga- and B-species [3] have also shown that this structure possesses promising activity and selectivity in the oxidative dehydrogenation (ODH) of propane.

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Oxidative Coupling of Methane over Sodium-Manganese Catalysts in the Presence of HCIcts and on the time-on-stream has been studied. Addition of HC1 into initial methane-oxygen mixture can increase selectivity to C. and decrease selectivity to carbon oxide’s formation. In the presence of HC1 the time-onstream increases to 35–40 h. On the basis of these results the mechanism of OCM reaction is also discussed.