Titlebook: Alkane C-H Activation by Single-Site Metal Catalysis; Pedro J. Pérez Book 2012 Springer Science+Business Media Dordrecht 2012 Alkane trans

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978-94-017-8187-9Springer Science+Business Media Dordrecht 2012

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Book 2012nation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. .The history of C-H bond activation, and the current research descri

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0920-4652 st with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. .The history of C-H bond activation, and the current research descri978-94-017-8187-9978-90-481-3698-8Series ISSN 0920-4652 Series E-ISSN 2215-180X

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Derivative-Free and Blackbox Optimizationevelopment of direct borylation of alkane C–H bonds catalyzed by transitional metal complexes since 1995. The scope of the reaction, mechanistic understanding via computational studies and kinetic experiments, and challenges for broader applications in practical organic synthesis are discussed.

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Building Linear and Quadratic Modelsin the C–H bond breakage. The chapter has been focused in systems that have specific synthetic and or biological relevance, and/or cases where well-defined transition metal catalysts have been studied.

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