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標(biāo)題: Titlebook: New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation; Rui Shang Book 2017 The Editor(s) (if app [打印本頁]

作者: 法庭    時間: 2025-3-21 18:50
書目名稱New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation影響因子(影響力)




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書目名稱New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation網(wǎng)絡(luò)公開度學(xué)科排名




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作者: 修剪過的樹籬    時間: 2025-3-21 23:39
Book 2017decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C–H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the i
作者: 干旱    時間: 2025-3-22 02:02

作者: 察覺    時間: 2025-3-22 07:48
Transition Metal-Catalyzed Decarboxylation and Decarboxylative Cross-Couplingslerance. In the present review, we summarize the various types of decarboxylative cross-coupling reactions catalyzed by different transition metal complexes. The scope and applications of these reactions are described. The challenges and opportunities in the field are discussed.
作者: Cerumen    時間: 2025-3-22 09:05
Palladium-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoester with Aryl and Alkenyl Halation shows that the decarboxylation on Pd(II) is the rate-determining step, with a transition state where Pd(II) has a five-coordination state. The calculated energy barrier of rate-determining step is about ~30?kcal/mol, which is in accordance with the optimized reaction temperature.
作者: Mundane    時間: 2025-3-22 16:14

作者: ABOUT    時間: 2025-3-22 19:23

作者: 頑固    時間: 2025-3-22 22:55
β-Arylation of Carboxamides Via Iron-Catalyzed C(sp3)–H Bond Activationial for the success of this reaction. This reaction shows selectivity for a primary C–H over a secondary one and is sensitive to steric factors on both the amide and the Grignard reagent. Various β-arylated aliphatic carboxamides can be readily prepared by using this method.
作者: 誤傳    時間: 2025-3-23 04:24
Springer Theseshttp://image.papertrans.cn/n/image/664887.jpg
作者: Overstate    時間: 2025-3-23 06:39

作者: 集合    時間: 2025-3-23 11:24
978-981-10-9813-0The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor
作者: 欲望小妹    時間: 2025-3-23 17:46
New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation978-981-10-3193-9Series ISSN 2190-5053 Series E-ISSN 2190-5061
作者: FOVEA    時間: 2025-3-23 21:39

作者: 狼群    時間: 2025-3-24 01:34
Construction of C(sp3)–C(sp2) Bonds Via Palladium-Catalyzed Decarboxylative Couplings of 2-(2-Azaaryly useful for the synthesis of some functionalized pyridines, quinolines, pyrazines, benzoxazoles, and benzothiazoles. Theoretical analysis shows that the nitrogen atom at the 2-position of the heteroaromatics directly coordinates to Pd(II) in the decarboxylation transition state.
作者: 為寵愛    時間: 2025-3-24 04:38
Palladium-Catalyzed Decarboxylative Couplings of Nitrophenyl Acetate Salts and Its Derivatives with des and chlorides. Because the nitro group can be easily converted to many other functional groups in synthetic organic chemistry, this reaction provides a new path for the synthesis of diverse functionalized 1,1-diaryl methanes and their derivatives.
作者: PACT    時間: 2025-3-24 09:46
Palladium-Catalyzed Decarboxylative Benzylation of α-Cyano Aliphatic Carboxylate Salts with Benzyl Eibits good functional group compatibility and proceeds under relatively mild conditions. A diverse range of quaternary, tertiary, and secondary β-aryl nitriles can be conveniently prepared by this method with good to excellent yield, and many of them are difficult to be synthesized by strong base-mediated nucleophilic substitution.
作者: 不合    時間: 2025-3-24 12:20
Recent Developments of Iron-Catalyzed Directed C–H Activation/C–C Bond Formation ReactionsDriven by the interest in chemical utilization of ubiquitous metals that are abundant and non-toxic, iron catalysis has become a rapidly growing area of research, and iron-catalyzed C–H activation is actively explored in recent years. In this chapter,?I?summarize the developments of iron-catalyzed C–H activation that emerged recently.
作者: 逃避現(xiàn)實    時間: 2025-3-24 15:41
Rui ShangNominated as an outstanding PhD thesis by the University of Science and Technology of China.Highlights a series of highly efficient decarboxylative coupling reactions that will be of interest to synth
作者: N防腐劑    時間: 2025-3-24 21:34

作者: 濕潤    時間: 2025-3-25 03:03
ethods are explained using practical examples and step-by-step analyses readily accessible for non-mathematicians. All of the novel chapters have been internationally published by the authors in peer-reviewed j978-94-007-9405-4978-94-007-2863-9
作者: defibrillator    時間: 2025-3-25 03:58
Rui Shangethods are explained using practical examples and step-by-step analyses readily accessible for non-mathematicians. All of the novel chapters have been internationally published by the authors in peer-reviewed j978-94-007-9405-4978-94-007-2863-9
作者: Mosaic    時間: 2025-3-25 11:22
Rui Shangethods are explained using practical examples and step-by-step analyses readily accessible for non-mathematicians. All of the novel chapters have been internationally published by the authors in peer-reviewed j978-94-007-9405-4978-94-007-2863-9
作者: Allodynia    時間: 2025-3-25 11:59

作者: 失敗主義者    時間: 2025-3-25 18:27
Rui Shangethods are explained using practical examples and step-by-step analyses readily accessible for non-mathematicians. All of the novel chapters have been internationally published by the authors in peer-reviewed j978-94-007-9405-4978-94-007-2863-9
作者: 災(zāi)禍    時間: 2025-3-25 23:54

作者: 天空    時間: 2025-3-26 00:36
Rui Shangethods are explained using practical examples and step-by-step analyses readily accessible for non-mathematicians. All of the novel chapters have been internationally published by the authors in peer-reviewed j978-94-007-9405-4978-94-007-2863-9
作者: 血友病    時間: 2025-3-26 06:01
Book 2017uable chemicals. In turn, the second part is devoted to several new C–C bond formation methodologies using the most ubiquitous transition metal, iron, as a catalyst, and using the ubiquitous C–H bond as the coupling partner..
作者: 脫離    時間: 2025-3-26 11:53

作者: 倔強(qiáng)不能    時間: 2025-3-26 14:02
Rui Shangadded after strict selection of the most valuable and promising novel methods. The novel methods are explained using practical examples and step-by-step analyses readily accessible for non-mathematicians. All of the novel chapters have been internationally published by the authors in peer-reviewed j
作者: 毀壞    時間: 2025-3-26 18:21

作者: Aviary    時間: 2025-3-26 22:06

作者: 易受騙    時間: 2025-3-27 05:04

作者: dandruff    時間: 2025-3-27 08:30

作者: Explicate    時間: 2025-3-27 11:11

作者: left-ventricle    時間: 2025-3-27 14:15

作者: 凝乳    時間: 2025-3-27 20:25
Transition Metal-Catalyzed Decarboxylation and Decarboxylative Cross-Couplingshat find versatile applications in the construction of carbon–carbon and carbon–heteroatom bonds. The use of relatively cheap and stable carboxylic acids to replace organometallic reagents enables the decarboxylative cross-coupling reactions to proceed with good selectivities and functional group to
作者: 一加就噴出    時間: 2025-3-28 00:10
Palladium-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoester with Aryl and Alkenyl Haction is potentially useful for laboratory-scale synthesis of aryl and alkenyl esters. Pd catalyst with bidentate phosphine ligands was found as the optimal catalyst, and unlike other reported decarboxylative couplings, copper is not needed as support catalyst in this reaction. The theoretical calcu
作者: 巨大沒有    時間: 2025-3-28 04:41
Synthesis of Polyfluorobiaryls via Copper-Catalyzed Decarboxylative Couplings of Potassium Polyfluorction can be used for the preparation of polyfluoroaromatic compounds and polyfluorostilbene. The reactants used in the reaction are easily accessible nonvolatile polyfluorobenzoate salts. Mechanistic studies suggest that decarboxylation occurs at first on copper(I) to generate a polyfluorophenylcop
作者: Vo2-Max    時間: 2025-3-28 07:29

作者: refraction    時間: 2025-3-28 12:44

作者: VOK    時間: 2025-3-28 18:33
Synthesis of α-Aryl Nitriles and α-Aryl Acetate Esters Via Palladium-Catalyzed Decarboxylative Coupls has been discovered. The reaction is competent for the synthesis of secondary, tertiary, and quaternary α-aryl nitriles utilizing cheap and low-toxic starting materials. This reaction is demonstrated to be useful to synthesize two drug molecules, Flurbiprofen and Anastrozole in gram scale, showcas
作者: reaching    時間: 2025-3-28 18:57
Palladium-Catalyzed Decarboxylative Couplings of Nitrophenyl Acetate Salts and Its Derivatives with des and chlorides. Because the nitro group can be easily converted to many other functional groups in synthetic organic chemistry, this reaction provides a new path for the synthesis of diverse functionalized 1,1-diaryl methanes and their derivatives.
作者: 種子    時間: 2025-3-29 01:12
Palladium-Catalyzed Decarboxylative Benzylation of α-Cyano Aliphatic Carboxylate Salts with Benzyl Eibits good functional group compatibility and proceeds under relatively mild conditions. A diverse range of quaternary, tertiary, and secondary β-aryl nitriles can be conveniently prepared by this method with good to excellent yield, and many of them are difficult to be synthesized by strong base-me
作者: Mangle    時間: 2025-3-29 05:14

作者: Hangar    時間: 2025-3-29 10:34

作者: BROOK    時間: 2025-3-29 14:25
Innovative because of its explanatory rather than mathematiThanks to the omnipresent computer, current statistics can include data files of many thousands of values, and can perform any exploratory analysis in less than seconds. This development, however fascinating, generally does not lead to simp
作者: RADE    時間: 2025-3-29 17:35
less than seconds. This development, however fascinating, generally does not lead to simple results. We should not forget that clinical studies are, mostly, for confirming prior hypotheses based on sound arguments, and the simplest tests provide the best power and are adequate for such studies. In
作者: 協(xié)迫    時間: 2025-3-29 22:51
Rui Shang Innovative because of its explanatory rather than mathematiThanks to the omnipresent computer, current statistics can include data files of many thousands of values, and can perform any exploratory analysis in less than seconds. This development, however fascinating, generally does not lead to simp
作者: photophobia    時間: 2025-3-30 01:59
Rui Shang Innovative because of its explanatory rather than mathematiThanks to the omnipresent computer, current statistics can include data files of many thousands of values, and can perform any exploratory analysis in less than seconds. This development, however fascinating, generally does not lead to simp
作者: graphy    時間: 2025-3-30 07:34
Rui Shang Innovative because of its explanatory rather than mathematiThanks to the omnipresent computer, current statistics can include data files of many thousands of values, and can perform any exploratory analysis in less than seconds. This development, however fascinating, generally does not lead to simp
作者: 圓錐體    時間: 2025-3-30 09:30
Rui Shang Innovative because of its explanatory rather than mathematiThanks to the omnipresent computer, current statistics can include data files of many thousands of values, and can perform any exploratory analysis in less than seconds. This development, however fascinating, generally does not lead to simp




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