標(biāo)題: Titlebook: Handbook of Fullerene Science and Technology; Xing Lu,Takeshi Akasaka,Zdenek Slanina Living reference work 20210th edition Fullerene.Carb [打印本頁] 作者: nourish 時間: 2025-3-21 18:53
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作者: 類型 時間: 2025-3-21 21:09 作者: 低能兒 時間: 2025-3-22 00:40
http://image.papertrans.cn/h/image/421352.jpg作者: Epithelium 時間: 2025-3-22 06:07 作者: BINGE 時間: 2025-3-22 09:32
https://doi.org/10.1007/978-3-8350-9294-5ch one or more carbons are replaced by other non-carbon atoms such as nitrogen. The addition pattern of exohedral modification on fullerenes is generally divided into monoaddition and multiaddition. In the case of monoaddition, C. has only two possible isomers, including 1,2- and 1,4-additions, but 作者: 深陷 時間: 2025-3-22 14:34 作者: constellation 時間: 2025-3-22 18:31
Studien zur Kommunikationswissenschaft reactions of fullerene dianions with O. and PhCN is also discussed, which afford a new type of fullerene oxazoline compounds. In addition, the application of electrochemistry for reaction mechanism study and heterocyclic rearrangement are discussed.作者: BILE 時間: 2025-3-22 21:45
https://doi.org/10.1007/978-3-322-89637-7c nitrogen is stable inside a fullerene molecule? Well, it turns out the nitrogen wave function just about “fits snugly” inside the fullerene cage. This chapter describes the different methods of production of ENFs. The properties and chemical functionalization of ENFs are also explored with the aim作者: 其他 時間: 2025-3-23 02:13
https://doi.org/10.1007/978-3-658-39647-3ergy level and molecular packing of fullerenes are major concerns and frequent subjects of investigation. In PSCs, on the other hand, a perovskite-structured compound is required in the active layer, so fullerenes are used as electron transport materials or dopants rather than as electron acceptors.作者: 我不死扛 時間: 2025-3-23 09:32 作者: theta-waves 時間: 2025-3-23 14:52 作者: Malaise 時間: 2025-3-23 21:21
https://doi.org/10.1007/978-3-662-58965-6r in an .-dichlorobenzene solution and a dimer in a solid. Terahertz absorption and dielectric behavior of [Li.@C.]X. were studied associated with the movement of the inner lithium ions in the fullerene cage.作者: 修飾語 時間: 2025-3-24 00:12 作者: Counteract 時間: 2025-3-24 02:49
https://doi.org/10.1007/978-3-642-16351-7ized fullerene–donor complexes has emerged as a promising alternative to create multifunctional nanomaterials. This chapter reviews some recent development on the preparation, structure, and properties of the self-assembled aggregates of fullerenes and their donor complexes and presents interesting 作者: Robust 時間: 2025-3-24 10:21
Living reference work 20210th edition future molecular memories, non-conventional materials for optoelectronics,and new treatments for civilization diseases. Offering a truly up-to-date critical survey of nanocarbon science, its concepts and highlights, it follows the concept of a handbook: it addresses key topics systematically, from 作者: 信徒 時間: 2025-3-24 10:41 作者: Conduit 時間: 2025-3-24 15:04
Chemical Reactions of Endohedral Metallofullerenes, and the electrochemical reaction have been successfully applied for the functionalization of EMFs, thereby affording many new structures with enhanced properties and promising applications. In this chapter, chemical reactions of EMFs, including classical EMFs and clusterfullerenes, are summarized.作者: conscience 時間: 2025-3-24 21:25
Chemical Reactivity and Addition Pattern on C60 and C70,ch one or more carbons are replaced by other non-carbon atoms such as nitrogen. The addition pattern of exohedral modification on fullerenes is generally divided into monoaddition and multiaddition. In the case of monoaddition, C. has only two possible isomers, including 1,2- and 1,4-additions, but 作者: 鞏固 時間: 2025-3-25 01:21
Complexation with Transition Metals, fashion, such as the typical μ.-η.:η.:η.-C. coordination seen in trinuclear complexes, and the binding mode could undergo a transformation to a mixed coordination of η. and η. through the insertion of ligands into the multinuclear clusters. Remarkably, some metal clusters act like bridges to link f作者: acheon 時間: 2025-3-25 05:59 作者: Nibble 時間: 2025-3-25 10:18 作者: Terminal 時間: 2025-3-25 12:57 作者: LEER 時間: 2025-3-25 18:09
Fullerenes Violating the Isolated Pentagon Rule,zed and characterized from C. to C.. These non-IPR fullerenes are vital for understanding the mechanism of fullerene formation, but also provide novel basic building blocks for fullerene materials. Based on the structures of prepared non-IPR fullerenes, the stabilization of fused pentagons was well 作者: Medicare 時間: 2025-3-25 20:52 作者: 一回合 時間: 2025-3-26 04:04
Introduction and Classification of Endohedral Metalfullerenes,he materials, biology, catalysis, photoelectric conversion, etc. Herein, a systematic and comprehensive summary of the new structures and unprecedented properties of EMFs are presented according to the categories of monometallofullerenes, dimetallofullerenes, trimetallofullerenes, and clusterfullere作者: aerobic 時間: 2025-3-26 08:19 作者: B-cell 時間: 2025-3-26 11:22 作者: PUT 時間: 2025-3-26 16:42
Self-Assembled Aggregates of Fullerenes,ized fullerene–donor complexes has emerged as a promising alternative to create multifunctional nanomaterials. This chapter reviews some recent development on the preparation, structure, and properties of the self-assembled aggregates of fullerenes and their donor complexes and presents interesting 作者: 不吉祥的女人 時間: 2025-3-26 17:24
Preparation, Extraction/Isolation from Soot, and Solubility of Fullerenes,作者: Apraxia 時間: 2025-3-26 21:22
ld.Shares firsthand experiences of leading international expNanocarbon chemistry and physics is a fast-developing, broad research area – the Nobel prizes in 1996 and 2010 awarded to two key discoveries in the field, and several other nanocarbon achievements of comparable importance. Owing to this ra作者: 悅耳 時間: 2025-3-27 04:30 作者: AROMA 時間: 2025-3-27 06:57 作者: cacophony 時間: 2025-3-27 12:47 作者: Cabg318 時間: 2025-3-27 13:47
https://doi.org/10.1007/978-3-663-09163-9ted from 1983 to 1990. In the beginning there were unexplained UV absorptions in the soot samples we had produced, and the endpoint was marked by the extraction of fullerenes in crystalline form and in form of coated films from just these samples.作者: 某人 時間: 2025-3-27 19:41 作者: fender 時間: 2025-3-27 22:42 作者: 責(zé)任 時間: 2025-3-28 03:21
Our Road to Fullerenes: A Personal Account,ted from 1983 to 1990. In the beginning there were unexplained UV absorptions in the soot samples we had produced, and the endpoint was marked by the extraction of fullerenes in crystalline form and in form of coated films from just these samples.作者: receptors 時間: 2025-3-28 09:06 作者: 我的巨大 時間: 2025-3-28 10:44
Living reference work 20210th editionield, and several other nanocarbon achievements of comparable importance. Owing to this rapid growth, the nanocarbon landscape fundamentally changes every few years, creating a need to survey the field on a regular basis to update the books that have become incomplete or even obsolete. As such, this作者: plasma 時間: 2025-3-28 17:24 作者: Emmenagogue 時間: 2025-3-28 21:49 作者: Parallel 時間: 2025-3-29 00:59 作者: reflection 時間: 2025-3-29 03:44
,Radical reaction?and Photoreaction,mation of C. by radical reaction?and photoreaction. Radical reaction?and photoreaction that are not covered in this chapter include reactions involving transition metals (see Chap. 3.7 for the reactions involving transition metals and Chap. 2.5 for the photochemical properties of C.).作者: 罐里有戒指 時間: 2025-3-29 10:13
Formation Mechanism of Fullerenes/Metallofullerenes,he discovery of multiple structural links among metallofullerene cage structures also suggests many fullerene and metallofullerene cages share the same stream of precursors. Understanding the formation of fullerenes and metallofullerenes will provide critical insights.作者: 不自然 時間: 2025-3-29 12:37 作者: effrontery 時間: 2025-3-29 19:24
https://doi.org/10.1007/978-3-322-90141-5fter, EMFs have attracted significant research attention. EMFs exhibit different physical and chemical properties compared to the empty fullerenes owing to their unique properties, including transferring electrons from the encapsulated metal or metal cluster to the fullerene cages. EMF derivatives h作者: 典型 時間: 2025-3-29 20:16
https://doi.org/10.1007/978-3-8350-9294-5tability of fullerene cages is the isolated pentagon rule (IPR). The chemical reactivity of fullerenes is similar to that of a fairly localized, electron-deficient polyolefin. Chemical modification of fullerenes is generally classified into exohedral modification and skeletal modification. Exohedral作者: hidebound 時間: 2025-3-30 03:07
https://doi.org/10.1007/978-3-476-04293-4structures and unique properties. So far, mononuclear, multinuclear metal complexes and ionic salts of fullerenes have been prepared by the reaction with metal clusters. The coordination reactions of C., higher fullerenes and metallofullerenes have usually shown very high regioselectivity to afford 作者: Hearten 時間: 2025-3-30 07:58 作者: ATP861 時間: 2025-3-30 08:34
Studien zur Kommunikationswissenschafte electrochemistry of fullerenes, attention is paid to the application of cyclic voltammetry in revealing the redox processes of fullerenes. The electrochemistry of different fullerenes is also discussed. As for the fullerene derivatives, the effects of the nature of addends, the number of addends, 作者: 小樣他閑聊 時間: 2025-3-30 14:35 作者: BARK 時間: 2025-3-30 17:54
https://doi.org/10.1007/978-3-663-05345-3nisms with various precursors, including small carbon fragments, polyaromatic hydrocarbons, and graphene, have been proposed and studied. Meanwhile, the discovery of multiple structural links among metallofullerene cage structures also suggests many fullerene and metallofullerene cages share the sam作者: 訓(xùn)誡 時間: 2025-3-30 21:20
Zurichtung und Prüfung des Leders -Textteils for drug discovery. However, one of the major issues that prevents the application of fullerenes in the biomedical field is their poor solubility in water, which is related to their high hydrophobic character. To overcome this issue, hydrophilic groups have been incorporated into the fullerene cor作者: Antecedent 時間: 2025-3-31 04:44 作者: CALL 時間: 2025-3-31 08:56
https://doi.org/10.1007/978-3-658-21122-6btained experimentally. It is due to the constraint of the isolated pentagon rule (IPR), which states that the fullerenes with isolated pentagons are stable, otherwise they are instable. The adjacent pentagons have unfavorable antiaromaticity and local strain. In terms of endohedral and exohedral de作者: 寬大 時間: 2025-3-31 12:02
https://doi.org/10.1007/978-3-322-84484-2 silicon and phosphorous nucleophiles, have been employed for the synthesis of a variety of fullerene adducts. In some cases, multiple adducts have been synthesized regioselectively. The second part deals with electrophilic reactions, although reported examples of these reactions are still limited. 作者: 譏諷 時間: 2025-3-31 17:03
https://doi.org/10.1007/978-3-658-04059-8ass of metallo-organic compounds, known as endohedral metallofullerenes (EMFs). These unique hybrid molecules are stabilized by charge transfer and subsequent coordination between the inner metallic units and the outer fullerene cages, which endow EMFs with characteristic physio-chemical properties 作者: acetylcholine 時間: 2025-3-31 18:04 作者: charisma 時間: 2025-4-1 01:29 作者: burnish 時間: 2025-4-1 02:56
https://doi.org/10.1007/978-3-663-09163-9 of a method for fullerene production in bulk amounts. These works opened the door for an entirely new branch of materials research and carbon chemistry. Recently, fullerenes were also detected in interstellar space. Presented are the various phases and steps of our work which with intermissions las作者: Cumulus 時間: 2025-4-1 09:13
https://doi.org/10.1007/978-3-322-85219-9 in 1993, many studies have been reported on the use of fullerenes (C. and C.) in photodynamic therapy (PDT). The advantages of fullerenes as photosensitizers (PSs) in PDT include high quantum yield in the generation of reactive oxygen species (ROSs) and a relatively long excitation wavelength; but 作者: 壁畫 時間: 2025-4-1 10:16
https://doi.org/10.1007/978-3-7091-7121-9he past three decades, researchers have developed different methods for the synthesis of endohedral metallofullerenes, including the Kr?tschmer-Huffman DC arc-discharge, laser ablation, radio frequency furnace, ion bombardment, and hot-atom chemistry method et al. Among them, DC arc-discharge method作者: chapel 時間: 2025-4-1 16:57 作者: NORM 時間: 2025-4-1 20:11 作者: 消瘦 時間: 2025-4-2 02:43 作者: 冒號 時間: 2025-4-2 05:50
Chemical Reactivity and Addition Pattern on C60 and C70,tability of fullerene cages is the isolated pentagon rule (IPR). The chemical reactivity of fullerenes is similar to that of a fairly localized, electron-deficient polyolefin. Chemical modification of fullerenes is generally classified into exohedral modification and skeletal modification. Exohedral
