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標(biāo)題: Titlebook: Essays in Structural Chemistry; A. J. Downs,D. A. Long,L. A. K. Staveley Book 1971 A. J. Downs, D. A. Long, L. A. K. Staveley 1971 chemist [打印本頁]

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作者: PET-scan    時間: 2025-3-21 22:11

作者: 香料    時間: 2025-3-22 04:02
Vibrational Assignments in Small Molecules,ecules having only three or four atoms and for some larger molecules if they possess sufficient symmetry. However, the complexity of the spectrum increases rapidly with each added atom, and unequivocal assignments are still sought for some molecules with as few as four and five atoms. The object is
作者: 幻想    時間: 2025-3-22 08:13
Interferometry: Experimental Techniques and Applications to Inorganic Structures,ely recently, experimental difficulties have prevented the determination of all the information which is, in principle, available from infrared and Raman spectra. In Raman spectroscopy the main restriction has been on the states of matter that could be studied; using the mercury arc as a source, onl
作者: 咽下    時間: 2025-3-22 12:01
Single-Crystal and High-Temperature Gas-Phase Raman Spectroscopy,hysical technique in chemistry. However, two major developments which have arisen from this application of lasers have yet to be widely used by chemists. They are gas-phase Raman spectroscopy (notably at temperatures above ambient) and oriented single-crystal Raman spectroscopy. It is probable that
作者: 礦石    時間: 2025-3-22 13:20

作者: 礦石    時間: 2025-3-22 20:27
Intermolecular Force Effects in the Raman Spectra of Gases,r study; for molecules in their ground electronic state, this requires ideally the investigation of Raman and infrared spectra of gases at low pressures where interactions are effectively absent. The other is associated with the effects of intermolecular forces and molecular motions on the spectrum.
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作者: 紳士    時間: 2025-3-23 03:49
,Structural Aspects of the M?ssbauer Effect,f γ-radiation can only be expected if the line-width of the incident radiation overlaps with that of the absorption line. According to previous work this would occur most readily at high temperature. At low temperature, therefore, loss of the resonance would be expected. In fact, M?ssbauer observed
作者: 設(shè)施    時間: 2025-3-23 05:59

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作者: essential-fats    時間: 2025-3-23 16:31
Vibrational Spectroscopic Studies of Complexes in Solution, of the experimental methods which have contributed to its development. Many types of investigation have been concerned primarily with the determination of the equilibrium concentrations of species and the deduction of related thermodynamic quantities, such as the enthalpies and entropies of complex
作者: 拱形面包    時間: 2025-3-23 18:17

作者: 輕率的你    時間: 2025-3-24 00:44

作者: Fluctuate    時間: 2025-3-24 05:22

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作者: intolerance    時間: 2025-3-24 12:37
,Structural Aspects of Sulphur—Fluorine Chemistry, stable to air and moisture. The lower valency states, by contrast, are readily hydrolyzed and the divalent compounds easily disproportionate. As a consequence of this sulphur hexafluoride has been a well established compound since it was first prepared by Moissan in 1900. Disulphur decafluoride was
作者: constitutional    時間: 2025-3-24 16:23
Book 1971ous chapters were chosen from friends, colleagues and past students of Len Woodward. It is our hope that the book will prove useful both to honours students and to research workers. We would like to thank all our contributors for their willing cooperation in this endeavour. We are also grateful to a
作者: mortuary    時間: 2025-3-24 21:19

作者: exhibit    時間: 2025-3-25 02:48
Dean S. Hartley III,Kenneth O. Jobsonts. They are gas-phase Raman spectroscopy (notably at temperatures above ambient) and oriented single-crystal Raman spectroscopy. It is probable that the investigation of matrix-isolated species by Raman spectroscopy will also become of importance in the characterization of unstable species and high temperature vapours.
作者: 停止償付    時間: 2025-3-25 05:29

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作者: 報復(fù)    時間: 2025-3-25 12:44
Single-Crystal and High-Temperature Gas-Phase Raman Spectroscopy,ts. They are gas-phase Raman spectroscopy (notably at temperatures above ambient) and oriented single-crystal Raman spectroscopy. It is probable that the investigation of matrix-isolated species by Raman spectroscopy will also become of importance in the characterization of unstable species and high temperature vapours.
作者: 分解    時間: 2025-3-25 19:07

作者: 跳動    時間: 2025-3-25 23:33

作者: glowing    時間: 2025-3-26 00:14

作者: Incompetent    時間: 2025-3-26 07:17
Michael B. Pursley,Thomas C. Royster and to various methylmercury(II) systems.. The concern with silyl compounds began with the investigation of trisilylamine.. A number of silyl derivatives of Group VI elements. as well as trigermyl-phosphine. have since been examined in Woodward’s laboratory.
作者: hieroglyphic    時間: 2025-3-26 11:10
Molecular Force Fields and Valency,d, and .. = .. - .., where .. is the equilibrium value of the . angle. There are two types of constants in equation (1.1): the main constants .. (bond) and .. (angle), and the interaction constants .. (bond-bond), .. (angle-angle) and .. (bond-angle).
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作者: gentle    時間: 2025-3-26 21:46
https://doi.org/10.1007/978-3-642-02693-5 in the study of the Raman spectra of cubic single crystals. In this chapter, it is proposed to give a historical review of studies of alkali halide crystals with special reference to the interpretation of experimental Raman data on the basis of lattice dynamics.
作者: 作嘔    時間: 2025-3-27 02:11
Cognitive Theory and Documentary Films readily form ‘a(chǎn)nomalous’ solid solutions with compounds of cations of different valency, thus necessarily disturbing the cation: anion ratio of the crystal as a whole, while preserving statistically the fluorite structure, or a structure formed from fluorite with a small distortion.
作者: exercise    時間: 2025-3-27 08:59
Intermolecular Force Effects in the Raman Spectra of Gases,s of the forces involved. Also, since many structural investigations have to be carried out with substances in the condensed phases, the effects of interactions on the molecular parameters should be known so that they can be eliminated if necessary.
作者: 四牛在彎曲    時間: 2025-3-27 13:32
Raman Spectra of Alkali Halides, in the study of the Raman spectra of cubic single crystals. In this chapter, it is proposed to give a historical review of studies of alkali halide crystals with special reference to the interpretation of experimental Raman data on the basis of lattice dynamics.
作者: concise    時間: 2025-3-27 16:54
Non-Stoichiometry in Fluorite Structures,s readily form ‘a(chǎn)nomalous’ solid solutions with compounds of cations of different valency, thus necessarily disturbing the cation: anion ratio of the crystal as a whole, while preserving statistically the fluorite structure, or a structure formed from fluorite with a small distortion.
作者: 指耕作    時間: 2025-3-27 21:08

作者: glucagon    時間: 2025-3-28 01:46
William M. Reynolds,Kevin D. Stark the chemist, the most useful expression for the force field is in terms of bond-length changes and bond-angle changes. The quadratic form for small displacements is then . where the summation is over all bonds and all interbond angles; .. = .. - .., where .. is the equilibrium length of the ith bon
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作者: 白楊    時間: 2025-3-28 18:11

作者: 萬靈丹    時間: 2025-3-28 21:32
https://doi.org/10.1007/978-3-642-71740-6n spectra can give information on moments of inertia, internuclear bond distances and angles, molecular symmetry and nuclear statistics. In this article, the progress of high-resolution Raman spectroscopy will be traced and an account given of the impact that has been made by recent discoveries and
作者: 包租車船    時間: 2025-3-28 23:40
https://doi.org/10.1007/978-3-642-11694-0r study; for molecules in their ground electronic state, this requires ideally the investigation of Raman and infrared spectra of gases at low pressures where interactions are effectively absent. The other is associated with the effects of intermolecular forces and molecular motions on the spectrum.
作者: 形容詞    時間: 2025-3-29 06:24
https://doi.org/10.1007/978-3-642-02693-5owever, in the case of cubic crystals, because of the symmetry properties, most and in some cases all the fundamental modes of vibration are inactive in the Raman effect. But they can manifest themselves as overtones and combinations in the second order Raman effect. Being a comparatively feeble phe
作者: tariff    時間: 2025-3-29 09:42
https://doi.org/10.1007/978-3-030-61736-3f γ-radiation can only be expected if the line-width of the incident radiation overlaps with that of the absorption line. According to previous work this would occur most readily at high temperature. At low temperature, therefore, loss of the resonance would be expected. In fact, M?ssbauer observed
作者: kindred    時間: 2025-3-29 11:40
Cognitive Theory and Documentary Filmordination number of eight. It has long been recognized that the resulting face-centred cubic structure of cations is essentially preserved over wide variations of the overall composition from MX.. The evidence is of two types. Oxides of transition metals having this structure—the actinide and rare
作者: Infinitesimal    時間: 2025-3-29 17:44
Cognitive Therapy with Couples, a ‘structure’ characterized by a range of coordination numbers and controlled very largely by the repulsive forces between the particles. The radial distribution curve of such a fluid shows a marked peak corresponding to the nearest neighbours of the central atom; subsequent peaks for second-neares
作者: 臭名昭著    時間: 2025-3-29 20:02
Analysis of Performance Metrics, of the experimental methods which have contributed to its development. Many types of investigation have been concerned primarily with the determination of the equilibrium concentrations of species and the deduction of related thermodynamic quantities, such as the enthalpies and entropies of complex
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作者: 宏偉    時間: 2025-3-30 09:45
A System for Object Class Detectionbutions to Raman spectroscopy should now stand as a starting point for surveying a large and rapidly growing area of the subject. In 1934 he demonstrated the diatomic nature of the mercurous ion by detecting an intense line at 169 cm. in the Raman spectrum of aqueous mercurous nitrate. However, only
作者: MONY    時間: 2025-3-30 15:24
Michael B. Pursley,Thomas C. Roysterigated in the laboratory of Dr. L. A. Woodward. The interest in the first group was initiated with the study of trimethylboron.. After this investigation was completed there was a natural extension to trimethyl-gallium and trimethylindium. and then subsequently to the dimethyl-thallium (III) cation.
作者: 骯臟    時間: 2025-3-30 17:47

作者: 被詛咒的人    時間: 2025-3-31 00:28
https://doi.org/10.1007/978-3-642-71740-6n spectra can give information on moments of inertia, internuclear bond distances and angles, molecular symmetry and nuclear statistics. In this article, the progress of high-resolution Raman spectroscopy will be traced and an account given of the impact that has been made by recent discoveries and advances in instrumentation.
作者: 他去就結(jié)束    時間: 2025-3-31 03:39
High-Resolution Raman Spectroscopy of Gases,n spectra can give information on moments of inertia, internuclear bond distances and angles, molecular symmetry and nuclear statistics. In this article, the progress of high-resolution Raman spectroscopy will be traced and an account given of the impact that has been made by recent discoveries and advances in instrumentation.
作者: Tremor    時間: 2025-3-31 06:01
https://doi.org/10.1007/978-1-4684-1902-3chemistry; lanthanum; metals; platinum; reproduction; spectroscopy; transition element; transition metal
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D. L. Forrest-Pressley,Laurie A. Gilliesctra of crystals (Chapters 5 and 8), and the investigation of vibrational Raman spectra in the vapour phase (Chapter 5). The general ease with which good quality Raman spectra can be obtained from very small quantities of imperfect samples using laser excitation will also be apparent from the relati
作者: 帽子    時間: 2025-4-1 04:12
Computer-Assisted Strategic Instructionts are frequently very uncertain. The tools which can be brought to bear in making a vibrational assignment include empirical correlations and the group frequency concept, infrared and Raman selection rules, molecular symmetry and group theory, theoretical band shapes for partially resolved bands, f
作者: Constant    時間: 2025-4-1 09:15
https://doi.org/10.1007/978-3-030-05114-3ibes the experimental determination of low-lying infrared frequencies using interferometric techniques and discusses the contributions such observations have made to the understanding of the vibrational spectra of selected species.
作者: Aggressive    時間: 2025-4-1 10:33
https://doi.org/10.1007/978-3-030-61736-3 overlap sufficiently for resonance to be obtained. This was the basis of the M?ssbauer discovery. In this article illustrations are given of how the technique may be used to investigate certain aspects of structural chemistry. Attention will be primarily confined to .Fe and .Sn on which most of the




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