標(biāo)題: Titlebook: Energetics of Organometallic Species; J. A. Martinho Sim?es Book 1992 Springer Science+Business Media Dordrecht 1992 Silane.chemistry.comb [打印本頁] 作者: Halloween 時(shí)間: 2025-3-21 18:49
書目名稱Energetics of Organometallic Species影響因子(影響力)
書目名稱Energetics of Organometallic Species影響因子(影響力)學(xué)科排名
書目名稱Energetics of Organometallic Species網(wǎng)絡(luò)公開度
書目名稱Energetics of Organometallic Species網(wǎng)絡(luò)公開度學(xué)科排名
書目名稱Energetics of Organometallic Species被引頻次
書目名稱Energetics of Organometallic Species被引頻次學(xué)科排名
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書目名稱Energetics of Organometallic Species年度引用學(xué)科排名
書目名稱Energetics of Organometallic Species讀者反饋
書目名稱Energetics of Organometallic Species讀者反饋學(xué)科排名
作者: chronology 時(shí)間: 2025-3-21 23:13 作者: 不足的東西 時(shí)間: 2025-3-22 03:28
https://doi.org/10.1007/978-3-531-93450-1r laboratories. This includes the substitution of one- and two-electron donors in 17-electron cation radicals by two-electron donor nucleophiles. Kinetic parameters show that both types of processes appear to involve 19-electron intermediates or transition states. Also included are some rather unusu作者: 協(xié)迫 時(shí)間: 2025-3-22 04:46 作者: palpitate 時(shí)間: 2025-3-22 11:07 作者: Trochlea 時(shí)間: 2025-3-22 16:43
Historical Perspective of Organometallic Thermochemistry,ies in specific MX. compounds. The results indicate that these, D., D.…. D., vary considerably from the mean value,..The main reason for variability in the individual D values in MX. compounds is that the valence-state of the metal changes in moving along the series MX., MX., MX.…. M. In the case of作者: Trochlea 時(shí)間: 2025-3-22 19:11
Electrochemistry of some Organic and Organometallic Radicals and their Application in Thermochemicaon, there appears to be very little three electron bonding interaction between the phosphorous atoms of tetraaryldiphosphine radical cations. This results in a modest weakening of the P-P bond relative to the neutral species..The standard potentials, E°, for the oxidation of the tributyl- and triphe作者: 催眠 時(shí)間: 2025-3-22 22:07 作者: Cryptic 時(shí)間: 2025-3-23 03:55
Bond Enthalpy Transferability - is it Achievable?, is a “weak” bond. This, in turn, is related to bond order: an interatomic bond of high order is both shorter and stronger than a bond of lower order between the same two elements. There is a lot of reliable experimental evidence to support these principles when elements of the first short period (n作者: Exaggerate 時(shí)間: 2025-3-23 05:57
Guided Ion Beam Studies of the Energetics of Organometallic Species,gths of bonds in coordinatively saturated metal-ligand compounds. Initial studies that address the metal-ligand bond energies in such species more directly include measurements of the sequential bond energies of M(CO). . (x = 1–6), M(H.0). . (x = 1–4) and M(CH.). . (x = 1–4). Variations in these bon作者: Pander 時(shí)間: 2025-3-23 11:41
1389-2185 a comprehensive and authoritative survey of problems found in the most classical of thermochemical techniques - combustion calorimetr- applied to organometallic978-94-010-5088-3978-94-011-2466-9Series ISSN 1389-2185 作者: Presbycusis 時(shí)間: 2025-3-23 16:19 作者: Ostrich 時(shí)間: 2025-3-23 19:18
https://doi.org/10.1007/978-94-011-2466-9Silane; chemistry; combustion; electrochemistry; metals; rhodium; transition metal作者: 污穢 時(shí)間: 2025-3-23 23:56 作者: 爭論 時(shí)間: 2025-3-24 05:34
https://doi.org/10.1007/978-3-322-81651-1The application of combustion calorimetry for determining enthalpies of formation of organometallic compounds is examined critically. The static-bomb method has been widely used but the results are generally disappointing whereas the rotating-bomb method is successful but has been used in only a few cases.作者: 緊張過度 時(shí)間: 2025-3-24 07:59
https://doi.org/10.1007/3-211-30869-5Rotating, aneroid combustion calorimetry combined with mass-loss, torsion Knudsen effusion is used to study the energetics of some organic compounds of Hg, Sn and Ge. Structural effects in some Cr, Mo and Cu compounds are also considered.作者: crescendo 時(shí)間: 2025-3-24 11:47
https://doi.org/10.1007/978-3-642-38039-6Literature methods that have been used to estimate the energetics of organometallic reactions are critically surveyed and illustrated with selected examples.作者: 有權(quán)威 時(shí)間: 2025-3-24 17:06 作者: Barter 時(shí)間: 2025-3-24 21:37
Combustion Calorimetry of Organometallic Compounds,The application of combustion calorimetry for determining enthalpies of formation of organometallic compounds is examined critically. The static-bomb method has been widely used but the results are generally disappointing whereas the rotating-bomb method is successful but has been used in only a few cases.作者: Coronation 時(shí)間: 2025-3-25 00:25
The Use of Calorimetric and Sublimation techniques to study Bond Properties in Organometallic CompoRotating, aneroid combustion calorimetry combined with mass-loss, torsion Knudsen effusion is used to study the energetics of some organic compounds of Hg, Sn and Ge. Structural effects in some Cr, Mo and Cu compounds are also considered.作者: conflate 時(shí)間: 2025-3-25 04:39
Estimates of Thermochemical Data for Organometallic Compounds,Literature methods that have been used to estimate the energetics of organometallic reactions are critically surveyed and illustrated with selected examples.作者: 四牛在彎曲 時(shí)間: 2025-3-25 10:55 作者: 嗎啡 時(shí)間: 2025-3-25 14:59
Selbstbestimmt bis nach dem Tods are used in deriving estimates of Rh—C bond dissociation enthalpies. Maximum Rh—C D values occur for the methyl and formyl derivatives (D(Rh-CH3~242 kJ mol. (58 kcal mol.); D(Rh-CHO=249 kJ mol. (59 kcal mol.)) where the steric demands of the organic fragments are minimized.作者: Oration 時(shí)間: 2025-3-25 18:22
Rh-C Bond Dissociation Enthalpies for Organometallic Derivatives of Rhodium Porphyrins,s are used in deriving estimates of Rh—C bond dissociation enthalpies. Maximum Rh—C D values occur for the methyl and formyl derivatives (D(Rh-CH3~242 kJ mol. (58 kcal mol.); D(Rh-CHO=249 kJ mol. (59 kcal mol.)) where the steric demands of the organic fragments are minimized.作者: 本土 時(shí)間: 2025-3-25 20:10
978-94-010-5088-3Springer Science+Business Media Dordrecht 1992作者: 兇猛 時(shí)間: 2025-3-26 01:01 作者: 處理 時(shí)間: 2025-3-26 06:26
,Warum brauchen Verk?ufer Selbst-PR?,nterest of thermochemists. Organometallic compounds were then of minor interest, and few such data had been measured. The development later of rotating bomb calorimetry, the use of combustion aids, advances in solution reaction calorimetry, and in particular, the adaptation of the Calvet twin-microc作者: AXIOM 時(shí)間: 2025-3-26 09:36
,Die Logik der bürgerlichen Demokratie,ent 5f as well as tetravalent (d°) group 4 complexes, patterns in metal-ligand o bond enthalpies are rather similar for a diverse range of ligands. This information is directly applicable to the analysis and invention of a variety of stoichiometric and catalytic transformations, including olefin hyd作者: 薄膜 時(shí)間: 2025-3-26 13:12
https://doi.org/10.1007/978-3-531-19691-6centers. Advances have been made in both understanding the interactions of hydrocarbons with metals and in the energetics of these interactions. We have examined reactions of a series of arenes with (C.Me.) Rh(PMe.) PhH and begun to map out the kinetic and thermodynamic preferences for arene coordin作者: 半球 時(shí)間: 2025-3-26 16:53
Selbstbestimmt bis nach dem Tods are used in deriving estimates of Rh—C bond dissociation enthalpies. Maximum Rh—C D values occur for the methyl and formyl derivatives (D(Rh-CH3~242 kJ mol. (58 kcal mol.); D(Rh-CHO=249 kJ mol. (59 kcal mol.)) where the steric demands of the organic fragments are minimized.作者: ALLEY 時(shí)間: 2025-3-26 21:33 作者: 谷類 時(shí)間: 2025-3-27 04:21 作者: Nonporous 時(shí)間: 2025-3-27 06:24
https://doi.org/10.1007/978-3-531-93450-1c voltammetry (CV). Redox potentials can be accurately determined for incorporation in thermochemical cycles that allow for the determination of thermodynamic quantities that are of interest to organometallic chemists. Applications towards the determination of solution bond dissociation energies and作者: 損壞 時(shí)間: 2025-3-27 11:21
Walzer: Vorstellungen zur Rolle der Frauis obtained by using a simple relationship based on the type and number of carbons present. Fusion enthalpies are estimated using a group additivity approach. Addition of vaporization and fusion enthalpies affords a sublimation enthalpy in good agreement with experiment. The standard error of this e作者: Etymology 時(shí)間: 2025-3-27 15:24 作者: Outwit 時(shí)間: 2025-3-27 19:38 作者: 古老 時(shí)間: 2025-3-28 01:14
7. Tag: Ruhen und neue Flugstrecken planen,nance mass spectrometry are described. In particular, sampling methods for typical compounds are mentioned along with approaches for determining the thermodynamics and kinetics of electron-transfer reactions. Results obtained recently for adiabatic ionization energies and electron attachment energie作者: 吹牛需要藝術(shù) 時(shí)間: 2025-3-28 03:32 作者: Ige326 時(shí)間: 2025-3-28 09:25 作者: 整理 時(shí)間: 2025-3-28 13:06
Management in EPU und Kleinstunternehmen,s, have been applied to examine the mechanism and energetics of organometallic reactions in the gas phase. These studies have provided a wealth of thermochemical data for organometallic species and have revealed important features of the potential energy surfaces associated with the reactions of hyd作者: Constitution 時(shí)間: 2025-3-28 16:10
https://doi.org/10.1007/978-3-663-08941-4n measured by using the technique of guided ion beam mass spectrometry. For species that form covalent bonds with the metals, the bond energies are found to correlate with the energy necessary to promote the bare metal atom or ion into an electron configuration suitable for bonding. The trends in th作者: Champion 時(shí)間: 2025-3-28 22:48 作者: HUMID 時(shí)間: 2025-3-28 23:32
Gas-Phase Acidities of Transition-Metal Carbonyl and Trifluorophosphine Hydrides,and decrease down a column in the periodic table. The periodic trends and substituent effects are discussed in view of the dependence of the acidity on the metal—hydrogen bond enthalpies and electron affinities of the resulting metal radicals. Solvation energies are also discussed.作者: 浮夸 時(shí)間: 2025-3-29 05:18 作者: anarchist 時(shí)間: 2025-3-29 09:16
?Ich kann stolz darauf sein, wer ich bin“ions used in estimation of these quantities. The article also explores the wider implications of the new numbers as well as some of the reasons for previous (erroneous) estimates. The continuing need for reliable (ancillary) enthalpies of formation is emphasised.作者: 晚間 時(shí)間: 2025-3-29 13:38 作者: faculty 時(shí)間: 2025-3-29 15:52 作者: alleviate 時(shí)間: 2025-3-29 23:40
Management in EPU und Kleinstunternehmen,rocarbons with atomic transition metal ions. The experimental methods and theoretical models used in these investigations are reviewed and presented along with representative results from recent studies.作者: 不合 時(shí)間: 2025-3-29 23:59 作者: neoplasm 時(shí)間: 2025-3-30 07:49
Solution Thermochemistry of Organometallic Compounds Using Photoacoustic Calorimetry: Enthalpies oflds of photosubstitution of each metal carbonyl in perfluorodecalin (PFD). In each case the quantum yield decreased a result attributed to the weak metal-PFD interaction. The PAC studies provide insight into the behavior of organometallic species, and the mechanistic significance of these results is considered.作者: avulsion 時(shí)間: 2025-3-30 10:00
https://doi.org/10.1007/978-3-531-19691-6he C-H activation/η.-coordination equilibria. We have begun to examine the reactions of rhodium isonitrile pyrazolylborates for alkane and arene C-H bond activation. A new, labile, carbodiimide precursor has been developed for these studies.作者: 不開心 時(shí)間: 2025-3-30 14:20 作者: 名字 時(shí)間: 2025-3-30 17:55
1389-2185 ontents correspond to the seventeen lectures delivered at the NATO ASI Energetics of Organometallic Species (Curia, Portugal, September 1991), plus three other invited contributions from participants of that summer school. These papers reflect a variety of research interests, and discuss results obt作者: 喚醒 時(shí)間: 2025-3-30 21:12
Walzer: Vorstellungen zur Rolle der Fraupproach. Addition of vaporization and fusion enthalpies affords a sublimation enthalpy in good agreement with experiment. The standard error of this estimation technique is 2.6 kcal/mole (10.9 kJ/mole) and compares with a standard experimental error of 1.74 kcal/mole (7.28 kJ/mole) obtained from a statistical analysis of literature data.作者: needle 時(shí)間: 2025-3-31 03:01
,Tag: Vertrauen – Wie man sicher landet,and decrease down a column in the periodic table. The periodic trends and substituent effects are discussed in view of the dependence of the acidity on the metal—hydrogen bond enthalpies and electron affinities of the resulting metal radicals. Solvation energies are also discussed.作者: Acquired 時(shí)間: 2025-3-31 05:33 作者: LAIR 時(shí)間: 2025-3-31 10:21 作者: 突襲 時(shí)間: 2025-3-31 15:36
Bonding and Solvation Energetics for Organometallic Gas-Phase Molecules and Ions: Experimental Apprs involving organometallic species are presented. Thermodynamic insights that arise from the experimental results are described, including applications to bond energetics, solvation, substituent effects, redox entropies, and thermodynamic effects in electron-transfer kinetics.作者: Mucosa 時(shí)間: 2025-3-31 19:05
Bond Strengths in Transition Metal Carbonyl Anions,. The bond energies can be combined with other thermochemistry to give neutral metal-carbonyl bond strengths, ionization potentials, metal-alkene bond energies, and limits on other metal-ligand bond strengths. The 14- and 16-electron metal carbonyl anions display systematically weaker bonds than the 13-, 15-, and 17-electron species.作者: Pert敏捷 時(shí)間: 2025-3-31 22:49 作者: 試驗(yàn) 時(shí)間: 2025-4-1 03:51
Book 1992rrespond to the seventeen lectures delivered at the NATO ASI Energetics of Organometallic Species (Curia, Portugal, September 1991), plus three other invited contributions from participants of that summer school. These papers reflect a variety of research interests, and discuss results obtained with作者: overrule 時(shí)間: 2025-4-1 09:26
Historical Perspective of Organometallic Thermochemistry,nterest of thermochemists. Organometallic compounds were then of minor interest, and few such data had been measured. The development later of rotating bomb calorimetry, the use of combustion aids, advances in solution reaction calorimetry, and in particular, the adaptation of the Calvet twin-microc作者: Microgram 時(shí)間: 2025-4-1 13:51 作者: 知識 時(shí)間: 2025-4-1 17:01
The Role of Bond Energies in Hydrocarbon Activation by Transition Metal Centers,centers. Advances have been made in both understanding the interactions of hydrocarbons with metals and in the energetics of these interactions. We have examined reactions of a series of arenes with (C.Me.) Rh(PMe.) PhH and begun to map out the kinetic and thermodynamic preferences for arene coordin作者: 慢慢沖刷 時(shí)間: 2025-4-1 20:06
Rh-C Bond Dissociation Enthalpies for Organometallic Derivatives of Rhodium Porphyrins,s are used in deriving estimates of Rh—C bond dissociation enthalpies. Maximum Rh—C D values occur for the methyl and formyl derivatives (D(Rh-CH3~242 kJ mol. (58 kcal mol.); D(Rh-CHO=249 kJ mol. (59 kcal mol.)) where the steric demands of the organic fragments are minimized.作者: Vulvodynia 時(shí)間: 2025-4-2 02:21
Solution Thermochemistry of Organometallic Compounds Using Photoacoustic Calorimetry: Enthalpies ofof the enthalpy of CO substitution on M(CO). (M = Cr, Mo, W) by heptane, CO substitution on Cr(CO). by amines (piperidine, .-butylamine, di-.-butylamine, tri-.-butylamine) and by weakly coordinating solvents (alkane, aromatic, and chlorocarbon solvents), and CO substitution on various metal carbonyl
